The low energy C IV dielectronic recombination (DR) rate coefficient associated with 2s→2p ∆n = 0 excitations of this lithiumlike ion has been measured with high energy-resolution at the heavy-ion storage-ring tsr of the Max-Planck-Institut für Kernphysik in Heidelberg, Germany. The experimental procedure and especially the experimental detection probabilities for the high Rydberg states produced by the recombination of this ion are discussed in detail. From the experimental data a Maxwellian plasma rate coefficient is derived with ±15% systematic uncertainty and parameterized for ready use in plasma modeling codes. Our experimental result especially benchmarks the plasma rate coefficient below 10 4 K where DR occurs predominantly via C III(1s 2 2p4l) intermediate states and where existing theories differ by orders of magnitude. Furthermore, we find that the total dielectronic and radiative C IV recombination can be represented by the incoherent sum of our DR rate coefficient and the RR rate coefficient of Pequignot et al. (1991, Astron. Astrophys., 251, 680).

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Dielectronic recombination (DR) of xenonlike W20+ forming W19+ has been studied experimentally at a heavy-ion storage-ring. A merged-beams method has been employed for obtaining absolute rate coefficients for electron-ion recombination in the collision energy range 0-140 eV. The measured rate coefficient is dominated by strong DR resonances even at the lowest experimental energies. At plasma temperatures where the fractional abundance of W20+ is expected to peak in a fusion plasma, the experimentally derived plasma recombination rate coefficient is over a factor of 4 larger than the theoretically-calculated rate coefficient which is currently used in fusion plasma modeling. The largest part of this discrepancy stems most probably from the neglect in the theoretical calculations of DR associated with fine-structure excitations of the W20+([Kr] 4d10 4f8) ion core.Comment: 7 pagers, 4 figures, accepted for publication in Physical Review

Until now, photodissociation studies on free complex protonated peptides were limited to the UV wavelength range accessible by intense lasers. We have studied photodissociation of gas-phase protonated leucine-enkephalin cations for vacuum ultraviolet (VUV) photons energies ranging from 8 to 40 eV. We report time-of-flight mass spectra of the photofragments and various photofragmentyields as a function of photon energy. For sub-ionization energies our results are in line with existing studies on UV photodissociation of leucine-enkephalin. For photon energies exceeding 10 eV we could identify a new dissociation scheme in which photoabsorption leads to a fast loss of the tyrosine side chain. This loss process leads to the formation of a residual peptide that is remarkably cold internally.

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