Experimental (FTIR, Raman, UV–visible and PL) and theoretical (DFT and TDDFT) studies on bis(8–hydroxyquinolinium) tetrachlorocobaltate(II) compound

Optical studies and dielectric response of [DMA]2MCl4(M = Zn and Co) and [DMA]2ZnBr4

“…[27][28][29] The observed band positions are very similar to those found in other materials containing organic-inorganic hybrid compound previously reported in the literature. 26,[30][31][32] As expected from some literature data, the corresponding transitions from the initial 4 A 2 ( 4 F) state into the excited states are grouped in Table 1. 30,32 It is also interesting to note that with respect to the mutual position of the bands, the [DMA] 2 CoCl 4 spectrum is very close to the [TMA]CoCl 4 spectrum.…”

Optical and electrical properties and conduction mechanism of [(CH3)2NH2]2CoCl4

“…Table presents the corresponding transitions from the initial 4 A 2 ( 4 F) state into the excited states, as expected from some literature data . These results are quite similar to those found for other previously reported MX 4 ‐containing organic–inorganic hybrids, such as [C 9 H 8 NO] 2 CoCl 4 , [C 8 H 10 NO] 2 CoCl 4 and [(CH 3 ) 4 N] 2 CoCl 4…”

Synthesis of a New Chloro Antimony Complex with Pyridinium Derivative: Crystal Structure, Hirshfeld Surface Analysis, Vibrational, and Optical Properties

“…According to some studies reported in the literature [2,[27][28][29][30][31][32][33][34][35] we can propose an attempt of assignment of the observed bands Table 3.…”

“…Generally, in the caption 4 pyridiniumethioamide, the stretching vibrations C-H are detected in the region 2787-3133 cm −1 [28][29][30][31][32]. These vibrations are observed in IR at 3133, 2991, 2869 and 2787 cm −1 , where the two bands at 2904, 2869 cm −1 are attributed to the (C-H) asymmetric and symmetric stretching vibrations, respectively [33,34].…”

“…S1). Moreover, the broad band observed in the 2991-2685 cm −1 spectral region, corresponds to the NH stretching vibrations interconnected by a system of hydrogen bonds in the crystal [28,32,34].…”