In this paper, the heat transfer characteristics of spray-wall impingement on a high temperature wall were studied by using a transient thermocouple and a one-dimensional finite-difference conduction model to obtain variations of wall temperature and heat flux. Results showed that increasing the injection pressure and decreasing the ambient temperature both caused an increase in surface heat flux and heat transfer coefficient. However, with the increase of the initial surface temperature from 200 to 600 °C, the surface heat flux and heat transfer coefficient first increased and then decreased, and reached the maximum at about 520 °C and 390 °C respectively, which was due to the change of heat transfer regime on the wall. The contribution of experimental factors descended in the order of initial surface temperature, injection pressure and ambient temperature. The dimensionless surface heat fluxes in terms of Biot and Fourier numbers were highly similar and a dimensionless correlation was developed to quantify this heat transfer behavior, which showed that the ratio of the thermal resistance of the high temperature wall to the thermal resistance of convection heat transfer on the wall surface changed almost linearly during the process of spray-wall impingement.