The influence of hydride exposure on previously unreported self-assembled InP(As) nanostructures is investigated, showing an unexpected morphological variability with growth parameters, and producing a large family of InP(As) nanostructures by metalorganic vapour phase epitaxy, from dome and ring-like structures to double dot in a ring ensembles. Moreover, preliminary microphotoluminescence data are indicating the capped rings system as an interesting candidate for single quantum emitters at telecom wavelengths, potentially becoming a possible alternative to InAs QDs for quantum technology and telecom applications.In the past few decades low-dimensional self-assembled quantum dots (QDs), as well as other zero/one dimensional nanostructures, have played an important role in studies of fundamental and applied physics 1 , being attractive, for example, for optoelectronic applications 2, 3 , as well for quantum information and computing 4,5,6 . The possibility to transition/transform from one nanostructure into another is a topic of particular interest, e.g. a dotlike shape can be made into a ring-like one, i.e. into quantum rings (QRs). 7,8,9,10,11,12,13,14,15,16 Considering AlInAs-InP structures, conventionally exploited in telecom applications, they show a peculiar type II band alignment, making them suitable for conventional opto-microelectronics 17 , while can also be an attractive option for "exotic" innovative applications with engineered band alignment. Some of us have shown unforeseen evidence 18 that the presence of Al0.48In0.52As, together with specific surface organization (and possible phase separation), has profound effects on the nucleation of InP (mono)layers. Indeed, InP deposited directly on lattice-matched AlInAs forms a variety of nanostructures, despite the nominally strain free environment. These structures, if capped, would generally result in a relatively broad type II emission around one micron, while preliminary transmission microscopy images show that the nanostructures evolve during capping, and are partially preserved after overgrowth.
19In this Letter, we report on the possibility of transforming these InP nanostructures grown by metalorganic vapour phase epitaxy (MOVPE) on lattice-matched InP substrates into variously shaped InP(As) emitters in the telecom windows. For example, InP(As) dots-to-rings transformation is carried out by intentional exposition to selected hydrides. Moreover, we observe a large phenomenology of a) Author to whom correspondence should be addressed. Electronic mail: enrica.mura@tyndall.ie 2 morphologies induced by growth conditions choice and post-growth layer exposure to hydrides that we critically discuss. Indeed the combination of arsenisation and cooldown protocols affects the final nanostructures' shape, changing the original dots into rings or domes (and others), conveying a rich variety of nanostructures in a controlled manner, and importantly engineering the photoluminescence characteristics, with specific configurations delivering clear signatu...