Experimental Investigation of the Solubility of Ammonia in Methanol

Schäfer, Dirk; Xia, Jianzhong; Vogt, Mathias; Kamps, and Álvaro Pérez-Salado; Maurer, Gerd

doi:10.1021/je700033y

Cited by 28 publications

(25 citation statements)

References 21 publications

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“…Thus solubility of hydrogen in gasoline was not studied in the research. Solubility of ammonia in ethanol and methanol has been studied in the literature at various temperatures and pressures [11,12,15]. Figure 09 summarizes the data reported in [11,12] for ammonia solubility in ethanol and methanol.…”

Section: Discussionmentioning

confidence: 99%

“…Solubility of ammonia in ethanol and methanol has been studied in the literature at various temperatures and pressures [11,12,15]. Figure 09 summarizes the data reported in [11,12] for ammonia solubility in ethanol and methanol. Molecular structure and the higher polarity can be considered as the primary reasons for higher solubility of ammonia methanol than that of ammonia in ethanol.…”

Section: Discussionmentioning

confidence: 99%

“…The larger cell was used to prepare feasible composite fuel blends in large quantities for engine dynamometer testing. The equipment was tested and calibrated according to the standard mentioned in literature [12,13]. Figure 2 shows a schematic diagram of VLE cell.…”

Section: Methodsmentioning

confidence: 99%

“…High pressure borosilicate glass view cells or high pressure thermostated vapor liquid equilibria (VLE) cells are the apparatus used for this research [11][12][13][14]. VLE cells are used in this research to measure the solubility of gaseous ammonia in liquid gasoline.…”

Section: Abstract: Ammonia When Blended With Hydro Carbon Fuels Canmentioning

confidence: 99%

“…Due to the higher polarity and shorter carbon chain methanol has higher emulsifying capabilities. Literature shows the solubility of ammonia in pure methanol is 258.1 g/l at 44.7 Psi and 313.75 K [12]. Despite the merits and demerits of ethanol and methanol they are used in the automotive industry as a transportation fuel [16].…”

Section: Abstract: Ammonia When Blended With Hydro Carbon Fuels Canmentioning

confidence: 99%

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Ammonia and gasoline composite liquid fuel blends emulsified with ethanol and methanol for direct displacement in internal combustion engines

Haputhanthri¹,

Austin²,

Maxwell³

et al. 2014

IOSRJMCE

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Section: Discussionmentioning

confidence: 99%

Section: Discussionmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

Section: Abstract: Ammonia When Blended With Hydro Carbon Fuels Canmentioning

confidence: 99%

Section: Abstract: Ammonia When Blended With Hydro Carbon Fuels Canmentioning

confidence: 99%

See 3 more Smart Citations

Ammonia and gasoline composite liquid fuel blends emulsified with ethanol and methanol for direct displacement in internal combustion engines

Haputhanthri¹,

Austin²,

Maxwell³

et al. 2014

IOSRJMCE

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Thermal conductivity of solid ammonia at low temperatures

Romanova

Stachowiak

Jeżowski

2013

Phys. Status Solidi B

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The results of measurements of the thermal conductivity dependence on temperature of pure ammonia crystal obtained in the temperature range 1.3–44 K have been shown. Quantitatively, the sample displays the thermal conductivity typical for a dielectric crystal. Below 2 K a singularity of the dependence of thermal conductivity coefficient on temperature was observed. The singularity was linked to the existence of TLS in the crystal. The analysis of the temperature dependence of the phonon mean free path in the NH3 crystal was also done.

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Reductive Amination of Aldehyde Ester from Vegetable Oils to Produce Amino Ester in the Presence of Anhydrous Ammonia

et al. 2016

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Reductive amination has been reported in the literature in the presence of amine or liquid ammonia and Ni catalysts for instance. However, to the best of our knowledge it is the first time that anhydrous ammonia was used to produce methyl‐9‐aminononanoate from methyl‐9‐oxononanoate in the presence of hydrogen, methanol and Pd/C catalyst. A yield of 74 % of the primary amino ester (methyl‐9‐aminononanoate) was obtained at 50 °C after 2 h of reaction under 100 bar of hydrogen in the presence of anhydrous ammonia. It was shown that in order to avoid the poisoning of the catalyst, anhydrous ammonia and hydrogen should be added at the beginning of the reaction to maintain the catalytic properties of Pd/C. Moreover, the catalyst was recyclable and the leaching of Pd was rather low under these conditions. These reaction conditions allow the formation of a renewable synthon which can be used in polymer industry.

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Experimental Investigation of the Solubility of Ammonia in Methanol

Cited by 28 publications

References 21 publications

Ammonia and gasoline composite liquid fuel blends emulsified with ethanol and methanol for direct displacement in internal combustion engines

Ammonia and gasoline composite liquid fuel blends emulsified with ethanol and methanol for direct displacement in internal combustion engines

Thermal conductivity of solid ammonia at low temperatures

Reductive Amination of Aldehyde Ester from Vegetable Oils to Produce Amino Ester in the Presence of Anhydrous Ammonia

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