Organic solutions are commonly used in frost-free air-source
heat
pumps (FFASHPs) due to their lower corrosiveness and cost-effectiveness.
However, there is a shortage of vapor pressure data for organic solutions,
which is crucial for their application in FFASHPs, particularly at
subzero temperatures. This paper developed an apparatus with low leakage
and good insulation for measuring vapor pressure using the static
method and proposed experimental procedures that included zero setting,
cleaning, drying, leak hunting, rinsing, multiple degassing, recording,
and remeasuring of discharged solutions. The reliability and accuracy
of the apparatus and procedures were verified by comparing experimental
data with standard data of distilled water from 278 to 323 K and pure n-heptane from 253 to 303 K. The equilibrium vapor pressures
of three organic solutions, namely, aqueous solutions of ethylene
glycol, glycerol, and triethylene glycol, commonly utilized in FFASHPs,
were measured in a temperature range of 253 to 323 K and a concentration
range of 0 to 54.5 wt %. A total of 199 data points were obtained,
ranging from 0.0858 to 12.3990 kPa, and fitted using modified Antoine
equations, with temperature and concentration serving as independent
factors. The mean absolute relative deviations between the experimental
and calculated data were determined to be 1.48, 2.35, and 2.13% for
aqueous solutions of ethylene glycol, glycerol, and triethylene glycol,
respectively. The study’s findings provide crucial data and
equations for the three organic solutions employed in FFASHPs.