The mobility of water
within the microstructure of hardened cement
paste has been at the center of a long-lasting debate, motivated by
the need to understand the fundamental mechanisms that play a role
in drying, shrinkage, creep, and thermal expansion. Our 1H NMR results show for the first time that externally applied pressure
can lead to migration of water within the microstructure (microdiffusion).
Upon compression, the gel water signal decreases. For the most part,
this is accommodated by a corresponding increase in the signal of
water in larger, interhydrate, and capillary spaces. However, there
is also an increase in the signal corresponding to the water in most
confined spaces. Normally, such tiny spaces are classified as hydrate
interlayers. However, we do not conclude that there is a significant
increase in interlayer water. Rather, we attribute this part of the
increase to a rearrangement of the microstructure upon compression
with some water confined in increasingly small gel pore spaces. These
findings show that the deformability of the microstructure (C–S–H
gel) at the expense of gel porosity may explain part of the macroscopic
deformations due to short-term creep.