Water
flow in a nanoscale channel is known to be affected by strong
water–wall interactions; as a result, the flow considerably
deviates from the conventional continuum flow. Nanochannel with a
sudden contraction or expansion is the most fundamental morphological
nanostructure in many nanoporous systems such as shale matrix, mudrock,
membrane, etc. However, the nanoconfinement effects of water flow
in nanoporous systems and its effect on macroscopic flow behavior
are still evolving research topics. In this work, our recently developed
pore-scale lattice Boltzmann method (LBM) considering the nanoscale
effects is extended to directly simulate water flow in nanoporous
systems. The results show that the flow rate is dramatically decreased
in hydrophobic nanopores because of additional flow resistances at
the contraction and expansion junctions. This indicates that the bundle
of capillary models or the permeability averaging method overestimates
the water flow rate in nanoporous media if the contraction/expansion
effects between different nanopores are ignored. This work highlights
the importance of wettability of the nanochannel in the determination
of dynamic water flow behaviors in the contraction/expansion nanosystem.
Other important aspects, including velocity distribution, flow patterns,
and vortex characteristics as well as pressure variation along the
flow direction, are for the first time revealed and quantified. Large
differences can be found comparing gas or larger-scale water flows
through the same system. A new type of pressure variation curve along
the axis of flow direction is found in the hydrophobic nanochannel
with a sudden contraction/expansion. This work provides the fundamental
understanding of water transport through the nanoscale system with
contraction and expansion effects, giving implications to a wide range
of industry applications.