In recent years, 2D materials including semimetallic graphene, semiconducting transition metal dichalcogenides (TMDs) and insulating h-BN have emerged as potential next generation electronic materials. For instance, semiconducting TMDs have been studied as channels in field effect transistors The memory window of floating gate (FG) type non-volatile memory (NVM) devices is a fundamental figure of merit used not only to evaluate the performance, such as retention and endurance, but also to discuss the feasibility of advanced functional memory devices. However, the memory window of 2D materials based NVM devices is historically determined from round sweep transfer curves, while that of conventional Si NVM devices is determined from high and low threshold voltages (V th s), which are measured by single sweep transfer curves. Here, it is elucidated that the memory window of 2D NVM devices determined from round sweep transfer curves is overestimated compared with that determined from single sweep transfer curves. The floating gate voltage measurement proposed in this study clarifies that the V th s in round sweep are controlled not only by the number of charges stored in floating gate but also by capacitive coupling between floating gate and back gate. The present finding on the overestimation of memory window enables to appropriately evaluate the potential of 2D NVM devices. (FETs), since their atomically thin nature can suppress the short channel effects that scaled Si-FETs have faced. [1-3] Not only n-MoS 2 FETs [4,5] but also ambipolar WSe 2 or MoTe 2 FETs [6-8] have been widely investigated from the context of channel mobility, contact engineering, etc. In addition, to explore their intrinsic properties due to the dangling bond free interface, 2D hetero-stack technology enables the fabrication of more advanced device structure [9] where insulating h-BN is applied as the atomically flat substrate [10,11] and gate insulator [12,13] with SiO 2 compatible permittivity (2-4). [14] As well as FETs, 2D materials have been utilized in non-volatile memory (NVM) devices, which are one of key building blocks for modern integrated circuits. [15,16] In particular, lots of efforts have been devoted to floating gate (FG) type memory devices. Their device structures have also evolved from the early stage of MoS 2 channel/HfO 2 tunnel barrier/multilayer graphene FG [17] stacks to recent 2D hetero-stack of WS 2 channel/h-BN tunnel barrier/graphite FG, [18] where the large memory window over 20 V for gate voltage (V G) range of ± 25 V and a good retention characteristic of 13% charge loss after 10 years have been demonstrated. Interestingly, many other 2D NVM devices, such as black phosphorus channel device and so on, [19-22] have also exhibited the large memory window, regardless of material systems, even though the origin has rarely been discussed. Moreover, 2D hetero-stacks have recently been further extended to artificial synaptic emulators for neuromorphic computing. [23] As mentioned above, the memory window, which is defined...