Firstly, I would like to express my sincere gratitude to my Doctoral Thesis Director Prof. Dr. Antonio Barrero Gil for the continuous support of my PhD study and related research, for his patience, motivation, and immense knowledge. His guidance and encouragement helped me in all the time of research and writing of this Thesis, also for the hard question which incented me to widen my research from various perspectives. I could not have imagined having a better advisor and mentor for my PhD study. My sincere thanks also goes to Prof. Dr. Ángel Velázquez and Prof. Dr. Juan Ramón Arias Pérez, who provided me an opportunity to join their research team as PhD candidate, and who gave access to the laboratory and research facilities. Without their precious support it would not be possible to conduct this research. I will always be thankful to Miguel de las Heras, Ricardo de las Heras and José Sánchez for their continuous support in the laboratory, which made such outstanding experimental facilities possible. They would always surpass the desired quality of the required experimental hardware. I would also like to thank my fellow labmates, Miguel Reyes Mata and Francisco Sastre Matesanz with whom I have spent so many years and David Vicente Ludlam who was always willing to give me a hand whenever I needed. This research has been funded by the international company REPSOL S.A., through the REPSOL-INSPIRE program and under contract P120130288. Through this program I was able to personally meet great professionals and people including Bernardo del Amo Fernández and Oscar Prieto Acedo. Last but not the least, I would like to thank my family: my partner Lorenzo, my parents, Menghua and Fenfang and my brother, Roberto, for supporting me throughout this Thesis and my life in general.