“…In its simplest form in ref [3,4], the closure for the reactive equation of state used the hypothesis of ideal energy mixing, pressure equilibrium p=p S =p G and same volume v=v S =v G (for simplicity). In the following we will keep pressure equilibrium p=p S =p G and ideal mixture hypothesis and investigate several closures either based on physical assumptions: -thermal equilibrium T S = T G , -isentropic reactants dS S = 0, or idealized assumptions:…”