Cellulose nanofiber (CNF) aerogels have the advantages
of being
eco-friendly, hydrophilic, and biocompatible and of having high porosity
and large surface area. but low mechanical durability is a main challenge.
In this regard, we proposed to fabricate a DF-x/CNF-y composite aerogel
through a directional freeze-drying method using down fiber (DF) as
the reinforcing filler and 1,2,3,4-butanetetracarboxylic acid (BTCA)
as the cross-linking agent. Due to the good compatibility between
DF and CNF, DF could effectively improve the strength of a composite
aerogel by dispersing stress along the pore wall. The DF-x/CNF-y composite
aerogel had significant longitudinal and transversal mechanical properties.
The presence of DF in the matrix promoted crystal nucleation and provided
a large surface area for crystal growth, which improved thermal stability
and thermal insulation performances of the composite aerogel. The
capillary effect of hollow DF and the interaction between DF and CNF
significantly enhanced the DF-x/CNF-y composite aerogel adsorption
performance. Methylene blue (MB) was chosen as a model pollutant.
The removal rate of MB correlated well with the pseudo-second-order
kinetics and Langmuir model (R
2 [0.9999]),
its maximum adsorption capacity for MB reached up to ∼250.21
mg/g. This work provides a strategy for the fabrication of a composite
aerogel, which might have potential application prospects such as
space, infrared stealth, water purification, and chemical contaminant
remediation.