Sediments contained in river channels are the products of physical erosion and chemical weathering of rocks outcropping in upstream catchments (e.g., Caracciolo, 2020;Weltje, 2012;Weltje & Eynatten, 2004). During transport, sedimentary geochemistry is altered by processes including chemical weathering (i.e., reaction of primary minerals with natural waters to form secondary minerals and solutes), sorting, cation-exchange, and selective transport/deposition (e.g., Bouchez et al., 2012;Tipper et al., 2021). As fluvial sediments can be transported on timescales of order 10 10 2 3 years, their geochemistry probably represents a spatial and temporal integration of catchment processes (Repasch et al., 2020). Consequently, they are frequently studied to understand the rates and location of chemical weathering, physical erosion and sediment transport (e.g.,