“…The small shoulder band at 1743 cm -1 was assigned to the carbonyl groups (C=O) due to the presence of acetyl ester and carbonyl aldehyde groups of hemicellulose [16,20]. The band at 1651 cm -1 was due to the bending mode of the absorbed water [21].…”
Section: Ftir Spectroscopy Analysismentioning
confidence: 99%
“…The mould was filled with a mixture of matrix and chopped Borassus fibers (diameter and length in the range of 0.10 to 0.15 mm and 2 to 3 cm, respectively) in random orientation with varying fiber content (4,8,12,16,20 and 24% by weight) and allowed to cure at room temperature for 24 h. The cured laminates were demolded and post cured in a hot air oven at100 o C for 3h. Laminates were made from epoxy resin and hardener taken in the ratio of 100 and 15 parts by weight, respectively.…”
Section: Formulation Of Compositesmentioning
confidence: 99%
“…The untreated fiber [ Fig. Also binding materials were partially removed and, as a result, the individual cellular part was exposed on the surface [20]. It is usual that sodium hydroxide is the most commonly 9 used chemical for leaching or cleaning the surface of natural fibers.…”
Section: Surface Topography Of Fibersmentioning
confidence: 99%
“…The bands at 1423, 1370, and 1317 cm −1 were assigned to the -CH2 scissoring, -OH bending vibration and C-H asymmetric deformation of cellulose, respectively [21]. An intense band at 1234 cm -1 was attributed to the -COO vibration of acetyl groups in hemicellulose [16,20]. The bands at 1152, 1103 and 1036 cm -1 were assigned to the C-O-C, C-O, C-C stretching of cellulose [16,21].…”
The aim of the present study was to investigate and compare the mechanical properties of untreated and chemically modified Borassus fiber reinforced epoxy composites.Composites were prepared by hand lay-up process by reinforcing Borassus fibers with epoxy matrix. To improve the fiber-matrix adhesion properties, alkali (NaOH), and alkali combined with silane (3-aminopropyltriethoxysilane) treatments on the fibers surface were carried out. Examinations through Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) were conducted to investigate the structural and physical properties of the Borassus fibers. Tensile properties such as modulus and strength of the composites made by chemically modified and untreated Borassus fibers Downloaded by [New York University] at 02:45 01 August 2015were studied using a Universal Testing Machine (UTM). Based on the experimental results, it was found that the tensile properties of the Borassus reinforced epoxy composites were significantly improved, as compared with the neat epoxy. It was also found that the fiber treated with combination of alkali and silane exhibited superior mechanical properties as compared with alkali and untreated fiber composites. The nature of fiber/matrix interface was examined through SEM of cryo-fractured samples.Chemical resistance of composites was also found to be improved with chemically modified fiber composites.
“…The small shoulder band at 1743 cm -1 was assigned to the carbonyl groups (C=O) due to the presence of acetyl ester and carbonyl aldehyde groups of hemicellulose [16,20]. The band at 1651 cm -1 was due to the bending mode of the absorbed water [21].…”
Section: Ftir Spectroscopy Analysismentioning
confidence: 99%
“…The mould was filled with a mixture of matrix and chopped Borassus fibers (diameter and length in the range of 0.10 to 0.15 mm and 2 to 3 cm, respectively) in random orientation with varying fiber content (4,8,12,16,20 and 24% by weight) and allowed to cure at room temperature for 24 h. The cured laminates were demolded and post cured in a hot air oven at100 o C for 3h. Laminates were made from epoxy resin and hardener taken in the ratio of 100 and 15 parts by weight, respectively.…”
Section: Formulation Of Compositesmentioning
confidence: 99%
“…The untreated fiber [ Fig. Also binding materials were partially removed and, as a result, the individual cellular part was exposed on the surface [20]. It is usual that sodium hydroxide is the most commonly 9 used chemical for leaching or cleaning the surface of natural fibers.…”
Section: Surface Topography Of Fibersmentioning
confidence: 99%
“…The bands at 1423, 1370, and 1317 cm −1 were assigned to the -CH2 scissoring, -OH bending vibration and C-H asymmetric deformation of cellulose, respectively [21]. An intense band at 1234 cm -1 was attributed to the -COO vibration of acetyl groups in hemicellulose [16,20]. The bands at 1152, 1103 and 1036 cm -1 were assigned to the C-O-C, C-O, C-C stretching of cellulose [16,21].…”
The aim of the present study was to investigate and compare the mechanical properties of untreated and chemically modified Borassus fiber reinforced epoxy composites.Composites were prepared by hand lay-up process by reinforcing Borassus fibers with epoxy matrix. To improve the fiber-matrix adhesion properties, alkali (NaOH), and alkali combined with silane (3-aminopropyltriethoxysilane) treatments on the fibers surface were carried out. Examinations through Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM) were conducted to investigate the structural and physical properties of the Borassus fibers. Tensile properties such as modulus and strength of the composites made by chemically modified and untreated Borassus fibers Downloaded by [New York University] at 02:45 01 August 2015were studied using a Universal Testing Machine (UTM). Based on the experimental results, it was found that the tensile properties of the Borassus reinforced epoxy composites were significantly improved, as compared with the neat epoxy. It was also found that the fiber treated with combination of alkali and silane exhibited superior mechanical properties as compared with alkali and untreated fiber composites. The nature of fiber/matrix interface was examined through SEM of cryo-fractured samples.Chemical resistance of composites was also found to be improved with chemically modified fiber composites.
“…The average crystalline size (D) of the AESF was computed by substituting the X-ray wavelength value as 0.154 nm in λ, K value as 0.94 (Scherrer constant), FWHM (full-width at half maximum) value at (1 0 1) crystallographic plane in β (radian), and θ value as Bragg's angle at peak intensity count in Scherer Equation (3) [36] . The computed crystalline size (D) of the AESF is 2.68 nm, which is lower than that of Napier grass fiber (2.83 nm) and rice straw (3.75 nm) [37] . The CrI and crystalline size influence the chemical reactivity and water absorption capacity of the fiber [8] .…”
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