We investigated the effect of a solvent on the metallorganic chemical vapor deposition ͑MOCVD͒ of Pb͑Zr, Ti͒O 3 ͑PZT͒ films by comparing conventional bubbling and sublimation delivery methods with one using liquid delivery where the source materials were dissolved in a solvent and vaporized in separate vaporizers. A Pb͑C 11 H 19 O 2 ) 2 -Zr͑O•t-C 4 H 9 ) 4 -Ti͑O•i-C 3 H 7 ) 4 -O 2 system was used as the source, while C 8 H 18 was used as the solvent together with C 4 H 8 O. The deposition rates of all constituent oxides decreased with the liquid-delivery method. Moreover, the process window to obtain stoichiometric PZT films ͓Pb/͑Pb ϩ Zr ϩ Ti) ϭ 0.5], irrespective of the supply rate of the Pb source, was diminished with the liquid delivery method, suggesting the contribution of the solvent on the deposition mechanism of PZT film. These phenomena were observed not only with C 8 H 18 but also when C 4 H 8 O was used as a solvent. Pb͑Zr, Ti͒O 3 ͓PZT͔ is a solid solution of PbTiO 3 and PbZrO 3 and has a perovskite structure. PZT films with thicknesses of less than 300 nm deposited on Si substrates have been used for nonvolatile memory ͑FeRAM, ferroelectric random access memory͒ applications. 1 Moreover, PZT thick films above 2 m in thickness have been investigated for use as optical waveguides 2 and in microelectromechanical system ͑MEMS͒ applications. 3 High-quality PZT films are essential in these applications and metallorganic chemical vapor deposition ͑MOCVD͒ is recognized as one of the most promising methods of deposition. This is because MOCVD-PZT films produce exceptional film quality together with good step conformability, a high deposition rate, and large areas of uniform film quality. 4 Two types of methods have been employed in PZT-MOCVD to obtain source gases that included Pb, Zr, and Ti elements. The first is the conventional bubbling and sublimation method where the vapor of the source gases, including the metal elements, is obtained by bubbling through an inert gas, or by sublimation where the vaporized elements are carried by the inert gas. [5][6][7] In this method of supply, only the carrier gas, such as Ar and N 2 , is supplied to the reaction chamber together with the source gases including the metal elements and the oxidant gas, such as O 2 . The other method, called the liquid-delivery source supply, is widely used to deposit PZT films by MOCVD,4,[8][9][10][11] where the source materials are dissolved into the solvent and vaporized at the vaporizer. The advantage of this is the increased deposition rate of films due to the increased rate of supply of the source gases to the reactor irrespective of their vapor pressure. Moreover, it is easy to precisely control the rate of supply of the source materials by measuring the solution, including the source materials, with a liquid mass-flow controller. In addition, the reliability of the precursor delivery is expected by alleviating the direct heating of the sources which usually degrades the source and diminishes the source vapor pressure with time. Ho...