Fabrication of Crumpled Ball-Like Nickel Doped Palladium-Iron Oxide Hybrid Nanoparticles with Controlled Morphology as Effective Catalyst for Suzuki–Miyaura Coupling Reaction

Abstract

Abstract:We report a facile synthetic strategy for nickel-doped palladium-iron oxide hybrid nanoparticles with controllable morphology. In this synthetic method, the morphology of the nanoparticles was regulated by the amount of triphenylphosphine used. When 1 mmol of triphenylphosphine was used as a capping agent, the main morphology of the nanoparticles was crumpled balls composed of nanosheets with an average particle size of 215 nm. The nanoparticles showed higher catalytic activity in the Suzuki-Miyaura coupling reaction than did other nanoparticles at equal amounts of Pd. This strategy allowed the reduction of the Pd loading in hybrid nanoparticles while still providing the performance level required for the reaction.

Facile Synthesis of a High Performance NiPd@CMK‐3 Nanocatalyst for Mild Suzuki‐Miyaura Coupling Reactions

“…In particular, mixing other elements with the precious Pd metal can modulate the elemental distribution on the surface, the intermetallic charge transfer, and the lattice strain . In recent years, NiPd bimetallic particles have shown their enhanced catalytic activity, even higher than that of single metal Pd particles, for carbon coupling reactions .…”

Recent Novel Hybrid Pd–Fe3O4 Nanoparticles as Catalysts for Various C–C Coupling Reactions

“…Transition metal and metal oxide nanoparticles often provide an alternative to noble metals, with easy availability and low cost [101,102]. In addition, the composition of bimetallic and trimetallic NPs hybrid NPs compared to monometallic NPs is very promising and synchronously benefits from increasing selectivity, efficiency, and stability, owing to synergistic substrate activation [39,86,101,[103][104][105]. NPs from transition metal loaded on hybrid Pd/Fe 3 O 4 have been developed by our group and include Cu/Pd-Fe 3 O 4 [38], Cu 2 O/Pd-Fe 3 O 4 [37], MnO/Pd-Fe 3 O 4 [36], CoO/Pd-Fe 3 O 4 [36], and Ni/Pd-Fe 2 O 3 [39].…”

“…In this review, we concentrate on latter exploitations in the synthesis of hybrid Pd-Fe3O4 nanocatalysts and various strategies for (1) urchin-like FePd-Fe3O4 for magnetic properties [31], (2) magnetically recoverable Pd-Fe3O4 hybrid nanocatalysts [32], (3) effectiveness of high metal-loaded NPs [7], (4) morphology impact of an organic capping agent of hybrid Fe3O4/Pd NPs [33], (5) roselike Pd-Fe3O4 hybrid nanocomposites of morphology control via thermal decomposition, and [34,35] (6) various transition metal-loaded Pd-Fe3O4 heterobimetallic nanoparticles (Scheme 1) [36][37][38][39].…”

Biogenic synthesis of palladium nanoparticles using Boswellia sarrata and their applications in cross‐coupling reactions

“…In the recent years, palladium nanoparticles (PdNPs) have garnered tremendous attention in heterogeneous catalysis due to their excellent catalytic activity. [ 19–25 ] In this regard, the green synthesis of PdNPs has attracted the vigil eye of attraction of nanotechnologists and material scientists, due to the growing environmental pollution caused by the conventional chemical methods. [ 26–31 ] Among various green recipes, biogenic synthesis of PdNPs [ 32–34 ] has recently emerged as an active area of research due to simplicity, cost‐effectiveness, higher potential of reduction, and low toxic effect on human health as well as on the environment.…”