2011
DOI: 10.1016/j.jcis.2011.06.011
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Fabrication of large scale two-dimensional colloidal crystal of polystyrene particles by an interfacial self-ordering process

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Cited by 46 publications
(47 citation statements)
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“…As an interesting observation, the agglomerations are already present when dispersing the particles in the LB trough. Based on our earlier studies, we determined that such behavior could be due to the surface hydrophobicity/degree of functionalization [3,56,59,60], as it has been shown that the strong hydrophobic interaction leads to clustering of the particles at the air-water interface.…”
Section: Resultsmentioning
confidence: 99%
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“…As an interesting observation, the agglomerations are already present when dispersing the particles in the LB trough. Based on our earlier studies, we determined that such behavior could be due to the surface hydrophobicity/degree of functionalization [3,56,59,60], as it has been shown that the strong hydrophobic interaction leads to clustering of the particles at the air-water interface.…”
Section: Resultsmentioning
confidence: 99%
“…We tested 2 Â 2 cm 2 and 4 Â 2 cm 2 sized substrates, as the LB trough cannot hold larger substrates. It is worth mentioning that a few groups that have succeeded in preparing PS monolayer on large surface area by using surfactants like TX 100, without using LB technique [56]. Vertical surface method [57], and vertical spreading [58] methods also have been reported without using LB technique, but their usage is limited to large size particles (hundreds of lm).…”
Section: Langmuir-blodgett Filmsmentioning
confidence: 99%
“…Direct assembly on water surface [45][46][47][48] Simple and fast process. Good two-dimensional closed pack array on water surface.…”
Section: Methods Remarksmentioning
confidence: 99%
“…The monolayer of particles is formed by first spreading a colloidal suspension onto the surface of water and then followed by compacting the particles on the water surface by using mobile arms, while at the same time monitoring the surface pressure to determine when the monolayer is closed packed. The direct interfacial self assembly of colloidal particles on the water surface transfer method is similar to the Langmuir-Blodgett technique in the sense that particles are spread on a water surface, but it differs in that, unlike the Langmuir-Blodgett technique, the particles self-organize into closed pack arrays by tuning the surface tension of water with surfactant, instead of physical compression using mobile arms [45,46,56]. Recently, Gao et al reported the use of the interfacial self assembly process to cover 1 m² glass substrate with a monolayer of polystyrene spheres, highlighting the immense scalability of the process ( Figure 4) [48].…”
Section: Methods Remarksmentioning
confidence: 99%
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