2011
DOI: 10.1246/bcsj.20110228
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Fabrication of Photochromic Tungsten Oxide Based Composite Film Using Peroxoisopolytungstic Acid

Abstract: Tungsten-based photochromic composite films were fabricated using peroxoisopolytungstic acid aqueous solution and transparent urethane resin. UV–visible irradiation of the resulting composite films showed photochromic properties, indicating broad absorption with peaks at 650 and 900 nm. The coloring time was about 40 min. The colored composite films were transformed to clear film in a dark room in 90 h.

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Cited by 21 publications
(3 citation statements)
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“…In addition, when the particle size in WO 3 and MoO 3 -based composite lm was in the order of sub nanometers, reversible photochromic properties were observed at room temperature. [10][11][12] Similarly, the presence of these nanometer size V 2 O 5 is considered to be responsible for the photochromic property of the composite lm, in the present study. Furthermore, other nano-composite lm fabrication methods have Fig.…”
Section: Resultsmentioning
confidence: 62%
“…In addition, when the particle size in WO 3 and MoO 3 -based composite lm was in the order of sub nanometers, reversible photochromic properties were observed at room temperature. [10][11][12] Similarly, the presence of these nanometer size V 2 O 5 is considered to be responsible for the photochromic property of the composite lm, in the present study. Furthermore, other nano-composite lm fabrication methods have Fig.…”
Section: Resultsmentioning
confidence: 62%
“…In this study, the absorbance of the films was calculated using the value of the transmittance. The method for calculating the photochromicreaction rate constant was described in a previous study [7]. The reaction rate equation is…”
Section: Resultsmentioning
confidence: 99%
“…38,39 The dielectric function for the tungsten oxide layer is modeled on work by Rottkay et al 40 who provided values in the oxidized and reduced states -those for the reduced state will be used here. 40,41 The permittivity for the polymer matrix will be taken to be 1.727 -an accepted value that will be assumed to be frequency independent even though absorption data shown in Fig. 4 indicate deviations in the ultraviolet.…”
Section: Modeling Of Core-shell Optical Responsementioning
confidence: 99%