Nonwoven face masks are being explored as potential multifunctional,
wearable, and smart healthcare devices. The fibers in the nonwoven
layers can effectively mechanically and electrostatically capture
submicrometer particles depending on their fiber size, porosity, and
surface charge. While surface charge enhances the filtration of mechanical
capture alone, charge is sensitive to moisture, heat, disinfectant
solvents, and storage. TriboElectric NanoGenerators (TENG) are a solution
to leverage the biomechanical action of respiration to generate a
skin-safe level of charge to maintain the electrostatic capture mechanism
throughout the wear cycle. In this study, hexadimethrine bromide (PB)
and poly(methyl vinyl ether-alt-maleic anhydride)
(PMA) were mixed with poly(vinyl alcohol) (PVA) and electrospun into
hybrid PVA nanofibers to compare their filtration performance to pure
PVA nanofibers. Fiber and pore size were measured from scanning electron
microscopy (SEM) images, fiber chemistry was characterized via Fourier
Transform InfraRed (FTIR) spectroscopy, TENG performance was measured
via output voltage, static and dynamic breathability were measured
via Air Permeability (AP) and in-line differential pressure (dP),
respectively, and filtration efficiency (FE) was calculated from penetrated
particle count during a simulated breathing experiment. Optimized
for fiber and pore size distributions, PVA fibers achieved 92.3% FE
of 0.3 μm particles and dP of 53.8 cm water, PVA/PB fibers achieved
92.5% FE and 18.3 cm water, and PVA/PMA fibers achieved 88.0% and
66.1 cm water. Output voltage was found to be dependent on moisture
content, with the pure PVA nanofibers generating the highest positive
voltage when wet, PVA/PMA nanofibers generating a less positive voltage,
and PVA/PB generating a negative voltage. The combination of filtration
and TENG performance positions both the pure and hybrid PVA nanofibers
for incorporation into a face mask as multifunctional nanofiber layers.
The hybrid PVA nanofibers specifically can be further tested as selective
capture membranes toward controlled adhesion, on-mask sample collection/preparation,
pathogen detection, and health data monitoring.