An iron-impeded geopolymer (Fe/GP) was synthesized from
natural
ferruginous kaolinite and optical waste for enhanced decontamination
of Congo red (CR) dye. The adsorption properties of Fe/GP were assessed
using an advanced monolayer equilibrium model of one energy (
R
2
> 0.99). Fe/GP possessed an active site
density
of 391.3 mg/g, which induced an adsorption capacity of 634 mg/g at
the saturation state. The number of adsorbed CR molecules per site
(
n
= 1.56–1.62) reflected the possible uptake
of two molecules per site via a multimolecular mechanism. The adsorption
energy (5.12–5.7 kJ/mol) reflected the physical adsorption
of the CR molecules via hydrogen bonding and/or van der Waals forces.
As a catalyst, notable activity toward photo-Fenton oxidation was
achieved even at high CR concentrations. Complete oxidation was observed
after 30 (CR concentration: 10 mg/L), 50 (20 mg/L), 80 (30 mg/L),
120 (40 mg/L), and 140 min (50 mg/L). High oxidation efficiency was
achieved using 0.1 g/L Fe/GP, 0.1 mL of hydrogen peroxide (H
2
O
2
), and a visible light source. Increasing the Fe/GP
dosage to 0.3 g/L resulted in complete oxidation of CR (100 mg/L)
after 220 min. Therefore, synthetic Fe/GP can be used as a low-cost
and superior catalyst and adsorbent for the removal of CR-based contaminants
via adsorption or advanced oxidation processes.