Facile fabrication of mixed samarium/tellurium metal–organic frameworks onto Ni foam and its outstanding cycling performance as binder-free battery-type electrode for supercapacitors
“…A bimetallic lanthanide MOF composed of samarium and thulium elements was directly grown on the surface of nickel foam by a simple electrochemical deposition method. 66 Besides the influence of the ligand and coordination, there are many ways to adjust the catalytic performance of MOFs. The required nanodots can be formed by means of interface etching and precipitation.…”
Metal-organic frameworks (MOFs) material are a kind of porous crystal material, which have been studied and applied in the field of energy storage, catalysis and separation. Rare earth MOFs are...
“…A bimetallic lanthanide MOF composed of samarium and thulium elements was directly grown on the surface of nickel foam by a simple electrochemical deposition method. 66 Besides the influence of the ligand and coordination, there are many ways to adjust the catalytic performance of MOFs. The required nanodots can be formed by means of interface etching and precipitation.…”
Metal-organic frameworks (MOFs) material are a kind of porous crystal material, which have been studied and applied in the field of energy storage, catalysis and separation. Rare earth MOFs are...
“…[24][25][26] With a nanoscale skeleton structured pore structure, high specic surface area and low solid density, they have shown excellent performance in adsorption, separation, catalysis and other aspects, and have become an investigation focus and frontier in the area of new materials. [27][28][29][30] The synthetic method of porous transition metal phosphide electrodes with MOFs as the precursor or template has also attracted extensive attention. Zhang et al prepared carbon coated CoP hollow spheres using cobalt-based MOFs as raw materials, delivering signicant specic capacitances and noticeable cycling stability.…”
Metal phosphide materials have drawn much attention due to their high supercapacitive activity. In this work, MOFs-derived carbon coated Cu3P with Ni doping (Cu3P/C-Ni) is prepared by using Cu-MOF-based precursor...
“…(iii) MOF formation:3M n + + n BTC 3− + x H 2 O → M 3 (BTC) n · x H 2 ONotably, although the cathodic deposition method has been performed in organic electrolytes by various researchers, 33–36 this method has been rarely applied in the synthesis of mixed metal MOFs from aqueous solutions. In this work, we addressed both these points to synthesise Ni,Mn-benzene-1,3,5-tricarboxylate (BTC) MOF via cathodic deposition from aqueous electrolyte.…”
In this work, we synthesized the Ni,Mn-MOF and C@NiMn2O4 materials onto the surface of nickel- foam (NF) support via a simple and scalable cathodic electrochemical deposition (CED) strategy followed by...
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