Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura coupling

Magnetically recoverable 2‐(aminomethyl)phenols‐modified nanoparticles as a catalyst for Knoevenagel condensation and carrier for palladium to catalytic Suzuki coupling reactions

“…Compared with the existing literature, the catalyst has the advantages of short reaction time, mild reaction conditions. [ 5,39 ] Importantly, in order to demonstrate the significance of the 2‐(aminomethyl)phenol functional group, an array of control experiments were carried out including employment of palladium immobilized on SMNPs‐NH 2 nanoparticles (SMNPs‐NH 2 ‐Pd) as the catalyst. The results showed that the reaction with SMNPs‐NH 2 ‐Pd as the catalyst could furnish the product with only 14% of yield which indicated that the 2‐(aminomethyl)phenol group grafted on SNMPs played a key role in loading of palladium nanoparticles.…”

“…Compared with the existing literature, the catalyst has the advantages of short reaction time, mild reaction conditions. [5,39] Importantly, in order to demonstrate the significance of the the catalyst could furnish the product with only 14% of yield which indicated that the 2-(aminomethyl)phenol group grafted on SNMPs played a key role in loading of palladium nanoparticles.…”

Green Synthesis, Functionalization and catalytic Activity of Palladium nanoparticles for development of Eco-friendly methods

“…Various examples of plant mediated green synthesis of PdNPs are shown in Table 1. 12 The mineral clay kaolinite has been used as supporting platform to synthesize PdNPs. The kaolinite is modified by grafting with amino alcohol triethanolamine and ionic liquid 1-(2-hydroxyethyl)-3-methylimidazolium to increase the compatibility and size controlled synthesis of PdNPs.…”

Palladium Supported on Porous Organic Polymer as Heterogeneous and Recyclable Catalyst for Cross Coupling Reaction

“…It remains a standing challenge to obtain stable Pd NPs with a narrow size and thus outstanding catalytic activity. In our previous studies, we reported several porous organic polymers with diverse linked groups and well-defined pore structures [ 34 , 35 , 36 ]. In order to continue our efforts to extend the catalytic application of heterogeneous Pd NP catalysts, herein, we report a Pd NP supported on an amide and ether functionalized porous organic polymer (Pd@AEPOP) as an efficient and recyclable catalyst for Heck and Suzuki coupling.…”