2015
DOI: 10.1155/2015/242798
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Facile Synthesis of Rambutan‐Like ZnO Hierarchical Hollow Microspheres with Highly Photocatalytic Activity

Abstract: Rambutan-like ZnO hierarchical hollow microspheres (ZnO HHMs) were constructed under hydrothermal conditions, using carboxyl methyl starch (CMS) as a soft template. The resulting products were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The experimental parameters and growth mechanism of rambutan-like ZnO HHMs were discussed in some detail. The as-prepared samples displayed improved photocatalytic activity for the degradation o… Show more

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Cited by 7 publications
(2 citation statements)
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“…This might have occurred because at higher temperatures the clusters adsorbed onto the crystal surface were more active, causing a higher surface-integration rate, which was significantly stronger than the solid-liquid mass transfer effect so that crystals had a tendency to increase. The Ostwald ripening mechanism also pointed out that a higher temperature could dissolve micro crystals, promote secondary nucleation of larger crystal nuclei, and as a result, increase the particle size of crystals 35 . In short, variations in reaction temperature had a bidirectional effect on the growth of struvite crystals, with a negative effect caused by the decrease of SI, and a positive effect caused by the increase of surface activity of crystals.…”
Section: Discussionmentioning
confidence: 99%
“…This might have occurred because at higher temperatures the clusters adsorbed onto the crystal surface were more active, causing a higher surface-integration rate, which was significantly stronger than the solid-liquid mass transfer effect so that crystals had a tendency to increase. The Ostwald ripening mechanism also pointed out that a higher temperature could dissolve micro crystals, promote secondary nucleation of larger crystal nuclei, and as a result, increase the particle size of crystals 35 . In short, variations in reaction temperature had a bidirectional effect on the growth of struvite crystals, with a negative effect caused by the decrease of SI, and a positive effect caused by the increase of surface activity of crystals.…”
Section: Discussionmentioning
confidence: 99%
“…Ju et al. prepared rambutan-like zinc oxide layered hollow microspheres using hydroxymethyl starch as a soft template [ 59 ]. The hard template method, also known as nano-casting [ 60 , 61 ], takes inorganic materials as templates, and the materials used for the template are mainly silicon dioxide, metal oxide, or a metal oxide skeleton.…”
Section: Processing Methods Of Microspheresmentioning
confidence: 99%