Reboilers are pivotal in the process of condensate oil stabilization, playing a significant role in reducing the vapor pressure to ensure product stability. The operational milieu of reboiler tube bundles is marked by extremities—high temperatures, elevated salinity, and the presence of dissolved oxygen—rendering them vulnerable to stress corrosion cracking. Such conditions can precipitate untimely degradation and disrupt production schedules. Addressing this, our research employed electrochemical noise measurement techniques to perform a statistical examination of the morphological characteristics of noise peaks, alongside time and frequency domain analyses for 2205 Duplex Stainless Steel(DSS), under an array of stress levels, ranging from 60%σs to 90%σs. Complementary Scanning Electron Microscopy analysis was utilized to discern microscopic changes pre- and post-corrosion exposure. Findings have demonstrated pronounced localized corrosion at each measured stress level, with localized corrosion index values spanning from 0.4290 to 0.9993. The presence of chloride ions was found to penetrate the passive film, selectively targeting the ferrite phase for pitting. Furthermore, the confluence of mechanical stress and corrosive elements facilitated the nucleation of crack tips, with oxygen and chloride ions synergistically escalating crack propagation. Our study concludes that the SCC of 2205 DSS follows a dual path: anodic dissolution alongside hydrogen embrittlement, culminating in surface pitting and intergranular cracking.