We present some applications of the deformation theory of toric Fano varieties to K-(semi/poly)stability of Fano varieties. First, we present two examples of K-polystable toric Fano
3
3
-fold with obstructed deformations. In one case, the K-moduli spaces and stacks are reducible near the closed point associated to the toric Fano
3
3
-fold, while in the other they are non-reduced near the closed point associated to the toric Fano
3
3
-fold. Second, we study K-stability of the general members of two deformation families of smooth Fano
3
3
-folds by building degenerations to K-polystable toric Fano
3
3
-folds.