The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6−0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We report observations of absorption in NH N = 1 ← 0, J = 2 ← 1 and ortho-NH 2 1 1,1 ← 0 0,0 . We also observed ortho-NH 3 1 0 ← 0 0 , and 2 0 ← 1 0 , para-NH 3 2 1 ← 1 1 , and searched unsuccessfully for NH + . All detections show emission and absorption associated directly with the hot-core source itself as well as absorption by foreground material over a wide range of velocities. All spectra show similar, non-saturated, absorption features, which we attribute to diffuse molecular gas. Total column densities over the velocity range 11−54 km s −1 are estimated. The similar profiles suggest fairly uniform abundances relative to hydrogen, approximately 6 × 10 −9 , 3 × 10 −9 , and 3 × 10 −9 for NH, NH 2 , and NH 3 , respectively. These abundances are discussed with reference to models of gas-phase and surface chemistry.