“…Optical refrigeration or laser cooling of solids based on the anti-Stokes luminescence was first proposed by Pringsheim in 1929. , Unlike the laser cooling of diluted atoms where the translational energy of atoms is removed via the interaction with the laser field, laser cooling of solids is achieved by taking away the lattice vibrational energy during the anti-Stokes emission process, i.e., annihilation of phonons. ,, To realize the laser cooling of solids, the material requires having high crystalline quality with properly spaced energy levels and high external quantum efficiency. , Due to those stringent requirements, laser cooling of solids experienced much greater challenges in materials than laser cooling of atoms. The net laser cooling of solids has not been achieved until 1995 when Epstein and co-authors demonstrated the first laser cooling in ytterbium-doped glasses .…”