We present a method for producing sub-100 fs electron bunches that are suitable for single-shot ultrafast electron diffraction experiments in the 100 keV energy range. A combination of analytical results and state-of-the-art numerical simulations show that it is possible to create 100 keV, 0.1 pC, 20 fs electron bunches with a spotsize smaller than 500 µm and a transverse coherence length of 3 nm, using established technologies in a table-top set-up. The system operates in the space-charge dominated regime to produce energy-correlated bunches that are recompressed by established radio-frequency techniques. With this approach we overcome the Coulomb expansion of the bunch, providing an entirely new ultrafast electron diffraction source concept.PACS numbers: 61.14. 87.64Bx, 41.75.Fr, 52.59.Sa The development of a general experimental method for the determination of nonequilibrium structures at the atomic level and femtosecond timescale would provide an extraordinary new window on the microscopic world. Such a method opens up the possibility of making 'molecular movies' which show the sequence of atomic configurations between reactant and product during bondmaking and bond-breaking events. The observation of such transition states structures has been called one of the holy-grails of chemistry, but is equally important for biology and condensed matter physics [1, 2].There are two promising approaches for complete structural characterization on short timescales: Ultrafast X-ray diffraction and ultrafast electron diffraction (UED). These methods use a stroboscopic -but so far multi-shot-approach that can capture the atomic structure of matter at an instant in time. Typically, dynamics are initiated with an ultrashort (pump) light pulse and then -at various delay times-the sample is probed in transmission or reflection with an ultrashort electron [3,4] or X-ray pulse [5]. By recording diffraction patterns as a function of the pump-probe delay it is possible to follow various aspects of the real-space atomic configuration of the sample as it evolves. Time resolution is fundamentally limited by the X-ray/electron pulse duration, while structural sensitivity depends on source properties like the beam brightness and the nature of the samples.Electron diffraction has some unique advantages compared with the X-ray techniques, see e.g. Ref.[6]. However, until recently femtosecond electron diffraction experiments had been considered unlikely. It was thought that the strong Coulombic repulsion (spacecharge) present inside of high-charge-density electron bunches produced through photoemission with femtosecond lasers fundamentally limited this technique to picosecond timescales and longer. Several recent developments, however, have resulted in a change of outlook. Three approaches to circumvent the space-charge problem have been attempted by several groups. The traditional way is to accelerate the bunch to relativistic energies to effectively damp the Coulomb repulsion. Bunches of several hundred femtosecond duration containi...