“…[2][3][4][5] This is particularly important when considering the combination of the aging process and fatigue loads. 6,7 The epoxy resin of composite materials can absorb moisture when in the presence of humid environments, which can be determined by the affinity of functional groups with a very polar nature obtained from the curing process of the epoxy resin. [8][9][10] Three distinct sorption methods were proposed by Apicella et al 11,12 The first is the dissolution of water in the polymer network in bulk, the second refers to moisture absorption onto the vacuoles' surface corresponding to the excess free volume of Nomenclature: CFRP, carbon fibre reinforced polymer; SLJ, single lap joints; ADCB, asymmetric double cantilever beam; Gth, fatigue threshold strain rate energy release; E, Young modulus; G, shear modulus; E 1 , normal direction; E 2 , transverse direction; E 3 , out-of-plane direction; M ∞ , infinite mass; M t , moisture uptake; w t , specimen mass; w 0 , initial constant mass the glassy structure, and the third considers the hydrogen bonding between polymer hydrophilic groups and water.…”