Feasibility of New Technology to Comprehensively Characterize Air Emissions from Full Scale Open Burning and Open Detonation

Abstract

Public reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing this collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information, including suggestions for reducing this burden to Department of Defense, Washington Headquarters Services, Directorate for Information Operations and Reports (0704-0188), 1215 Jefferson Davis Highway, Suite 1204, Arlington, VA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to any penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number. PLEASE DO NOT RETURN YOUR FORM TO THE ABOVE ADDRESS. REPORT DATE (DD-MM-YYYY) REPORT TYPE ERDC-CERL TR-09-DRAFT SPONSORING / MONITORING AGENCY NAME(S) AND ADDRESS(ES)Strategic Environmental Research and Development Program (SERDP) 901 North Stuart Street, Suite 303 Arlington, VA 22203 SPONSOR/MONITOR'S ACRONYM(S) SERDP SPONSOR/MONITOR'S REPORT NUMBER(S)Weapons Systems and Platforms Project WP-1672 DISTRIBUTION / AVAILABILITY STATEMENTApproved for public release; distribution is unlimited. SUPPLEMENTARY NOTES ABSTRACT See Attached SUBJECT TERMSOpen burning, Open detonation, OB/OD, Optical remote sensing, LIDAR, Air quality characterization, Emission factor, Aerial measurement, in-situ measurement, Particulate matter (PM), PM-2.5, PM-10 The project team developed a field campaign plan and conducted the field campaign at Tooele Army Depot, Utah, in March 2010. Emissions from OB of M1 propellant and OD of TNT were sampled over a three week period. This report describes the execution and results of the field campaign and discusses the feasibility of the emission measurement system to characterize air emissions from full-scale OB/OD. Close coordination with the DoD demilitarization community enabled the research team to produce useful data for demilitarization-related compliance issues and operations.The feasibility study consisted of in situ and optical remote sensing (ORS) sampling, analysis and monitoring. The in situ sampling configuration included fixed position samplers, and airborne sampling. The aerial platform used a balloon-lofted instrument package called the "Flyer". The instrument pack was lofted with a He-filled balloon and maneuvered by two tethers connected to two all-terrain-vehicles (ATVs). Continuous measurements of CO 2 and co-sampled PM-10, volatile organic compounds, and semi-volatile organic compounds allowed determination of emission factors.The ORS system included active and passive open-path Fourier Transform Infrared (OP-FTIR) spectrometers, Ultraviolet Differential Absorption Spectrometers (UV-DOAS), and a Micropulse LIght Detection And Ranging (LIDAR) (MPL). The ORS samplers were complemented with Tapered Elemental Oscillating Microbalance (TE...

Per‐ and polyfluoroalkyl substances (PFAS) exposure through munitions in the Russia–Ukraine conflict

“…Figure 1 depicts the probable transport of PFAS after detonation and their fate in several compartments. Published studies have explored chemical and particulate dispersion patterns after detonation of surface‐level and buried munitions (Aurell et al, 2015; Kim et al, 2016); however, available studies of PFAS aerosol dispersion have been limited to industrial factories with elevated stacks (D'Ambro et al, 2021; Kim et al, 2016; Shin et al, 2011). These studies suggest that PFAS may be directly inhaled by those in the vicinity of the detonation.…”

Innovative Technology Development for Comprehensive Air Quality Characterization from Open Burning

“…WP-1672 consisted of in-situ and optical remote sensing (ORS) sampling, analysis, and monitoring (Kim et al, 2010). The final technical report is available at the SERDP/ESTCP web site (http://www.serdp.org/content/download/9560/122378/file/WP-1672-FR.pdf).…”