We performed photoluminescence ͑PL͒ and degenerate four-wave-mixing ͑FWM͒ spectroscopy in epitaxially laterally overgrown GaN at 10 K. Optical transitions based on exciton complexes such as biexciton emission, exciton-exciton scattering, electron-hole plasma, and so on, were revealed by PL under a wide range of excitation densities. The FWM signals were observed from states below the fundamental excitonic absorption edge, showing that nonlinear photoswitching can be performed with a transmittance geometry. The origin of such nonlinearlity was discussed by correlating with feasible many-body effects between excitons, biexcitons, and free carriers.