“…For the last few decades, self-assembling materials represent a fascinating area of dynamic research, which provides a highlighted approach for design of new structures with predefined functionality [ 7 , 10 , 11 , 12 , 13 ]. Chiral smectic liquid crystalline (LC) materials belong to one of the most exciting classes of such organic materials that are able to self-assemble in a polar layered structure of nanometer scale [ 11 , 13 , 14 , 15 , 16 , 17 , 18 ]. The self-organization structure of such compounds, and hence their favorable electro-optic, structural, and dielectric properties, can be adjusted by a proper design of molecular architecture build up from various units [ 15 , 19 , 20 , 21 , 22 , 23 , 24 ].…”