“…Oxide nanostructures have been extensively explored due to their potential applications in various fields, such as sensors, catalysis, field emission, energy storage and conversion, optoelectronics, magneto-electronics, magneto-optics, and microelectronics, etc. − So far, oxide nanostructures are focused mostly on transition metal oxides, particularly on those with relatively simple ingredients and structures. − Of great interest is molybdenum trioxide because it has different crystalline phases with open structures which make it possible to be applied in different fields. − Molybdenum trioxide is revealed to have several polymorphs: the well-known thermodynamically stable α-MoO 3 (space group Pnma ), metastable β-MoO 3 ( P 2 1 / c ), ε-MoO 3 ( P 2 1 / m ), and hexagonal metastable h -MoO 3 ( P 6 3 / m ) . However, all the polymorphs reported are basically constructed merely in different ways based on the building block of MoO 6 octahedron (see Figure S1, Supporting Information).…”