The synthesis of the azobenzene gelator has already been reported [10a]. To prepare a self-assembled cholesteric gel, a homogeneous mixture of BL006/ R811/gelator was obtained by first dissolving all compounds in a common solvent, tetrahydrofuran (THF), and then evaporating the solvent under reduced pressure. The mixture was flow-filled, at 130 C, into the 10 lm thick electrooptic cell, and subsequent fast cooling of the mixture to room temperature resulted in the gel sample with a uniform physical network built up from nanometer-sized hydrogen-bonded fibrous aggregates (Fig. 1a). To record a grating, a photomask was positioned on one side of the cell, and the whole was placed into a thermostat hot stage and heated to the recording temperature. A curing system (Novacure apparatus) was used to expose the sample to UV light centered at 360 nm. Once the irradiation was completed, the sample was cooled to room temperature, either under irradiation or with irradiation turned off. The gratings were observed on a polarizing optical microscope (Leitz DMR-P apparatus). For SEM observations of the aggregates, on a Hitachi S-4700 FEG SEM apparatus, the cell was carefully opened and the cholesteric LC host was extracted in hexane.For the measurements of the diffraction efficiency under an electric field, a He±Ne laser (633 nm) was used as the incident light source (normal to the cell) and the 1st order (+1) diffraction signal, I d , was monitored using a high-speed photodetector (Displaytech) collected to a digital oscilloscope (Tektronix, TDS 420 A apparatus). A high-voltage waveform generator (WFG500 apparatus, FLC Electronics) was used to apply the AC (1000 Hz), square wave, and pulse electric fields through the cell. The diffraction efficiency was calculated as the ratio of I d over the intensity of the laser beam before reaching the cell.