Printable electron field emitters could lead to cheap and scalable large area electron sources. This paper presents work on electron field emission from water-based multiwall carbon nanotube (MWCNT) dispersions, and introduces new results on emission from different substrates. We summarize work in which MWCNTs are deposited onto paper, glass, and plastic substrates, and show that the field emission characteristics can be tailored by controlling the underlying morphology as well as by post-laser irradiation. We also show that engineering the work function of MWCNTs can significantly enhance field emission, and that resonant tunneling effects may be induced by suitable surface functionalization. Electrons are traditionally confined to the surface of bulk materials by an energy barrier roughly equivalent to the work function (φ). They can be thermally excited over this barrier at very high temperatures, in a process known as thermionic emission. However, a more subtle, controllable, and faster means of overcoming the potential barrier at room temperature is to make use of quantum mechanical tunneling. The vacuum energy level in materials is normally flat. However, by applying an electric field one can distort the barrier observed by electrons at the surface, to mimic a triangular potential barrier. Increasing the electric field makes this barrier thinner, and eventually electrons can tunnel from the Fermi level energy states of a metal or semi-conductor into vacuum. This is the basis of electron field emission. The FowlerNordheim equation 1 describes the behavior of a generalized field emitting system, where J is the field emission current density, φ is the work function, and the constants a and b are 1.54 × 10 −6 A(eV)V −2 and 6.83 × 10 9 (eV) −3/2 Vm −1 , respectively. 1 The enhancement factor (β) is the factor by which the local electric field at the emitting surface enhances the applied electric field (E), and combines various effects including geometric field enhancement, dielectric field enhancement, and field screening. This enhancement factor depends critically on the surface geometry of an emitter.From this equation it is clear that the field emitted current can be increased by: i) increasing the applied electric field, ii) decreasing the work function, and iii) increasing the enhancement factor, or by a combination of any of the above factors. By plotting ln(J/E 2 ) against 1/E, a "Fowler-Nordheim" plot is obtained, with a gradient of -bφ 3/2 /β, from which β can be calculated. Applications of electron field emission include all fields in which an electron source is required; from flatscreen displays (analogous to flat cathode ray tubes), 2 X-ray sources, 3 field emission microscopy, 4 electron-beam lithography, 5 microwave generation, 6 and space-vehicle thruster charge neutralization.
7The covalent bonding in carbon nanotubes (CNTs) makes them ideal field emission materials, with high aspect ratio, strength, stability, electronic conductivity, small diameter and extended length. Most studies focus on al...