The influence of metastable centres on the phonon emission of highly planar-doped GaAs:Si is studied by time of flight measurements. A general decrease of the flux of ballistically propagating phonons is observed in the whole investigated range of electric fields. It is assumed to be mainly caused by a redistribution of emitted phonons due to the creation of vibronic states. An additional channel of the emission of quasi-diffusively propagating phonons appears on account of the formation of metastable centres and their decay according to a dynamic balance.