2021
DOI: 10.1039/d1dt02413b
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Field-induced single-ion magnet based on a quasi-octahedral Co(ii) complex with mixed sulfur–oxygen coordination environment

Abstract: Synthesis and characterization of structure and magnetic properties of the quasi-octahedral complex (pipH2)[Co(TDA)2] 2H2O (I), (pipH22+ = piperazine dication, TDA2-= thiodiacetic anion) are described. X-ray diffraction studies reveal the first...

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Cited by 9 publications
(1 citation statement)
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“…These features are responsible for the extensive study of its complexes as candidates to mononuclear SMMs. [35][36][37][38][39][40][41][42] Indeed, six-coordinate Co(II) mononuclear complexes showing octahedral (O h ), [43][44][45] trigonal prismatic (TP) 46,47 or trigonal antiprismatic 48 coordination geometries are very good candidates for single-molecule magnets (SMMs). Usually, the octahedral complexes show a uniaxial anisotropy (D < 0) and only occasionally an easy-plane anisotropy (D > 0), but in all cases, the zfs is large.…”
Section: Synthesis and Characterization Of The Cobalt(ii) Complexmentioning
confidence: 99%
“…These features are responsible for the extensive study of its complexes as candidates to mononuclear SMMs. [35][36][37][38][39][40][41][42] Indeed, six-coordinate Co(II) mononuclear complexes showing octahedral (O h ), [43][44][45] trigonal prismatic (TP) 46,47 or trigonal antiprismatic 48 coordination geometries are very good candidates for single-molecule magnets (SMMs). Usually, the octahedral complexes show a uniaxial anisotropy (D < 0) and only occasionally an easy-plane anisotropy (D > 0), but in all cases, the zfs is large.…”
Section: Synthesis and Characterization Of The Cobalt(ii) Complexmentioning
confidence: 99%