2018
DOI: 10.17951/l.2017.15.2.37
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Filmowa neoawangarda i początki sztuki video

Abstract: <p>Artykuł w syntetyczny sposób omawia najważniejsze zjawiska filmu eksperymentalnego w kontekście pojęcia i praktyki sztuki neoawangardowej od II połowy lat 60. do połowy lat 70. XX wieku. Na początku przypomniana została pierwsza i druga faza rozwoju filmu eksperymentalnego w związku z istnieniem tzw. Wielkiej Awangardy oraz z działalnością jej kontynuatorów po Ii wojnie światowej w USA. Nastepnie zdefiniowane zostało pojęcie neoawangardy w odniesieniu do ujęcia, które zparoponował Frank Popper. W dals… Show more

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“…With the largest radius of any metal studied, this may be due to lanthanum's ability to host larger coordination numbers where increased solvent coordination may temper the metal-macrocycle interaction. 50,51 This outlier aside, the Δδ of both 1 H and 13 C resonances shows only a very modest dependence on the identity of the metal ion, mirroring the trends in cyclization temperature and suggesting structural similarity across the f block for complexes of the same anion. Combined, these observations show that the degree of electron density at the alkyne carbons is controlled by the relative Lewis acidity of the cation, which is in turn modulated by the basicity of the anion.…”
Section: Anion Control Of Thermal Reactivitymentioning
confidence: 91%
See 1 more Smart Citation
“…With the largest radius of any metal studied, this may be due to lanthanum's ability to host larger coordination numbers where increased solvent coordination may temper the metal-macrocycle interaction. 50,51 This outlier aside, the Δδ of both 1 H and 13 C resonances shows only a very modest dependence on the identity of the metal ion, mirroring the trends in cyclization temperature and suggesting structural similarity across the f block for complexes of the same anion. Combined, these observations show that the degree of electron density at the alkyne carbons is controlled by the relative Lewis acidity of the cation, which is in turn modulated by the basicity of the anion.…”
Section: Anion Control Of Thermal Reactivitymentioning
confidence: 91%
“…31,32,47,48 In general, control of the bite angle of an enediynebearing ligand alters the interalkynyl distance, consequently tuning the barrier to Bergman cyclization. In the lanthanide arena, the nuclear penetration of the f electrons renders ligand field theory moot, 49,50 and the extent of metal-ligand interaction is strongly tempered by the affinity of the accompanying anion. 51 Therefore, in this study, the coordination strength of the anion was varied to tune the degree of the lanthanide-macrocycle interaction in order to evaluate the effects on the Bergman cyclization temperature of the complex.…”
Section: Anion Control Of Thermal Reactivitymentioning
confidence: 99%