ABSTRACT:We study the thermocapillary-driven spreading of a droplet on a nonuniformly heated substrate for fluids associated with a non-monotonic dependence of the surface tension on temperature. We use lubrication theory to derive an evolution equation for the interface that accounts for capillarity and thermocapillarity. The contact line singularity is relieved by using a slip model and a Cox-Voinov relation; the latter features equilibrium contact angles that vary depending on the substrate wettability, which, in turn, is linked to the local temperature. We simulate the spreading of droplets of fluids whose surface tension−temperature curves exhibit a turning point. For cases wherein these turning points correspond to minima, and when these minima are located within the droplet, then thermocapillary stresses drive rapid spreading away from the minima. This gives rise to a significant acceleration of the spreading whose characteristics resemble those associated with the "superspreading" of droplets on hydrophobic substrates. No such behavior is observed for cases in which the turning point corresponds to a surface tension maximum.
■ INTRODUCTIONThe motion of sessile droplets over liquids and solids is of central importance to a number of industrial applications such as coating flow technology, inkjet printing, microfluidics and microelectronics, and medical diagnostics. Despite the apparent simplicity of the physical setup involved, this motion is rather complex and some of its aspects remain poorly understood; in particular, the mechanisms underlying the dynamics of the threephase contact line are still the subject of debate. In view of its complexity 1 and its practical importance, droplet motion has received considerable attention in the literature and has been the subject of two major reviews. 2,3 In this work, we consider the motion of sessile droplets on non-isothermal solid walls, driven by thermocapillarity. The walls underlying the droplets are subjected to a temperature gradient which induces surface tension gradient-driven droplet deformation and migration from low to high surface tension regions. Thermocapillary-driven droplet motion was studied by Bouasse 4 who demonstrated the possibility of inducing droplet-climbing on a heated wire, against the action of gravity, by heating its lower end. Studies involving horizontal substrates have shown that, unless the magnitude of the imposed temperature gradient is sufficiently large, no droplet motion is possible due to contact angle hysteresis, while under certain conditions, steady migration of droplets has been shown. 5,6 A number of studies have examined the thermocapillary motion of droplets theoretically. Brochard 7 determined the spreading characteristics of a wedge-shaped drop in the presence of chemical or thermal gradients via local force and energy balances. This work was generalized by Ford and Nadim 8 to arbitrary, two-dimensional droplet shapes and different contact angles at the two contact lines. Lubrication theory was used to describe the...