Using a recently proposed solution for an open antiferromagnetic spin-1/2 XXZ quantum spin chain with N (even) spins and two arbitrary boundary parameters at roots of unity, we compute the boundary scattering amplitudes for one-hole states. We also deduce the relations between the lattice boundary parameters appearing in the spin-chain Hamiltonian and the IR (infrared) parameters that appear in the boundary sine-Gordon S matrix. 1 β 2 = 8(π − µ) 2 Very recently, similar relations were found for the open XXZ spin chain with diagonal-nondiagonal boundary terms in [16]. 3 In fact, there is a change ξ ± → −ξ ± in the Bethe equation for the diagonal case [11].