2016
DOI: 10.1002/2016gl068499
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First airborne samples of a volcanic plume for δ13C of CO2 determinations

Abstract: Volcanic degassing is one of the main natural sources of CO2 to the atmosphere. Carbon isotopes of volcanic gases enable the determination of CO2 sources including mantle, organic or carbonate sediments, and atmosphere. Until recently, this work required sample collection from vents followed by laboratory analyses. Isotope ratio infrared analyzers now enable rapid analyses of plume δ13C‐CO2, in situ and in real time. Here we report the first analyses of δ13C‐CO2 from airborne samples. These data combined with … Show more

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Cited by 44 publications
(40 citation statements)
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“…These constraints, coupled with those from the CO 2 /S and CO 2 /Nb ratios, point to primary arc magmas containing up to 1 wt% CO 2 (Box 4), an order of magnitude higher than that of average mid-oceanridge basalt (MORB; about 1,000 ppm) 93 . Volcanic-arc data are still sparse, however, and portable mass spectrometers mounted on helicopters 94 and field vehicles 95 are providing new methods for carbon isotope analysis in remote regions. Carbon isotope measurements in springs are also revealing subducting and upper-plate sources, as well as sequestration in the biosphere 96 .…”
Section: Carbon Returned: Volcanic Gasmentioning
confidence: 99%
“…These constraints, coupled with those from the CO 2 /S and CO 2 /Nb ratios, point to primary arc magmas containing up to 1 wt% CO 2 (Box 4), an order of magnitude higher than that of average mid-oceanridge basalt (MORB; about 1,000 ppm) 93 . Volcanic-arc data are still sparse, however, and portable mass spectrometers mounted on helicopters 94 and field vehicles 95 are providing new methods for carbon isotope analysis in remote regions. Carbon isotope measurements in springs are also revealing subducting and upper-plate sources, as well as sequestration in the biosphere 96 .…”
Section: Carbon Returned: Volcanic Gasmentioning
confidence: 99%
“…High latitude volcanoes, such as those of the Aleutian Arc, outgas low fluxes of carbon (Fischer, 2008;Aiuppa et al, 2017;Lopez et al, 2018); these volcanoes are associated with the subduction of seafloor sediments dominated by carbon-poor diatomaceous and terrigenous material (Johnston et al, 2011). The sedimentary composition is reflected in the carbon isotopic composition, which lies within mantle values (Kodosky et al, 1991;Symonds et al, 2003;Fischer and Lopez, 2016). Latitude, a key control on sediment compositions, may therefore modulate the magnitude of carbon outgassing from arc volcanoes.…”
Section: Arc Volcanismmentioning
confidence: 99%
“…millimetre-to centimetre-accuracy point measurements using a total station or real-time kinematic global navigation satellite system (RTK-GNSS) receivers) but provide either sparse coverage or are limited in extent. Airborne surveys using conventional crewed aircraft have provided high-resolution measurements of volcanic gas composition and flux at several remote and explosive volcanoes [Doukas and McGee 2007;Fischer and Lopez 2016;Gerlach et al 1997;Gerlach et al 1998;Ilyinskaya et al 2018;Kelly et al 2013;Shinohara et al 2003;Werner et al 2011;Werner et al 2013;Werner et al 2017]. However, the limited availability of crewed aircraft, and their associated high costs, complex planning and logistics requirements, and restrictions in hazardous areas, mean that regular surveys [e.g.…”
Section: Measurement Requirements In Volcanologymentioning
confidence: 99%
“…Samples of several hundred millilitres are usually necessary to obtain accurate isotopic ratios, requiring pumped sampling over several tens of seconds. Traditional ground-based methods of direct sampling involve filling glass vials or bottles from fumaroles [Giggenbach 1996] but, more recently, lightweight Tedlar® or ALTEF gas bags (Figure 2A) have also provided adequate sampling volumes from horizontally dispersing dilute ground-level plumes [Malowany et al 2017] or high altitude plumes by airborne sampling from a helicopter [Fischer and Lopez 2016]. A dilute ascending plume at Stromboli volcano has also been successfully sampled using such bags deployed via UAS [Stix et al 2018a].…”
Section: Volcanic Gas Samplingmentioning
confidence: 99%