We propose the intensity mapping of the redshifted H i 21-cm signal from the post-reionization epoch as a cosmological probe of f (R) gravity. We consider the Hu-Sawicki family of f (R) gravity models characterized by a single parameter f,R0. The f (R) modification to gravity affects the postreionization 21-cm power spectrum through the change in the growth rate of density fluctuations. The quantity of interest is the redshift space distortion parameter βT (k, z) which imprints the change. We find that a radio interferometric observation at an observing frequency 710MHz with a SKA-1-Mid like radio telescope may measure the binned βT (k) at a level of sensitivity to distinguish f (R) models with log 10 |f,R0| > −5 at a > 5 − σ level in the k range k > 0.4M P c −1 . We find that using a Fisher matrix analysis the 68% bound obtained on the parameter is −5.62 < log 10 |f,R0| < −4.38 which is competitive with other probes of f (R) gravity. Thus the future observation of the post-reionization H i signal holds the potential to put robust constraints on f (R) gravity models and enrich our understanding of late time cosmic evolution and structure formation.