Flame retardancy effect of melamine cyanurate in combination with aluminum diethylphosphinate in a fully waterborne epoxy system

Aljamal, Amer; Marosi, György; Szolnoki, Beáta

doi:10.1080/10426507.2021.2021525

Cited by 3 publications

(3 citation statements)

References 9 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[14][15][16][17] As a typical phosphate-based flame retardant, aluminum diethylphosphonate (ADP) had the advantages of good thermal stability, high flame retardant efficiency, low smoke density and easy processing, [18][19][20] which let it become one of the research hotspots of phosphate-based flame retardants, and some research achievements had been made. [21][22][23] Layered silicate was a kind of clay mineral with lamellar structure, and the lamellar scale was nanoscale, 24,25 which addition to the polymer could improve the mechanical, thermal stability and flame retardant properties of the polymer. 26,27 Kaolin (Kaol) was one of layered silicates, which had a certain barrier property, 28 and had synergistic flame retardant effect when added Kaol and flame retardant at the same time in polymers.…”

Section: Introductionmentioning

confidence: 99%

“…Melamine cyanurate was a nitrogen‐based flame retardant with the advantages of high nitrogen content, low toxicity, low smoke and high flame retardant efficiency, 11–13 which could be used to improve the flame retardancy of polymers 14–17 . As a typical phosphate‐based flame retardant, aluminum diethylphosphonate (ADP) had the advantages of good thermal stability, high flame retardant efficiency, low smoke density and easy processing, 18–20 which let it become one of the research hotspots of phosphate‐based flame retardants, and some research achievements had been made 21–23 . Layered silicate was a kind of clay mineral with lamellar structure, and the lamellar scale was nanoscale, 24,25 which addition to the polymer could improve the mechanical, thermal stability and flame retardant properties of the polymer 26,27 .…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Preparation and property analysis of kaolin/melamine cyanurate/aluminum diethylphosphinate/recycled PET composites

Fang

2023

J of Applied Polymer Sci

View full text Add to dashboard Cite

In the plastic industry, recycling waste plastic was an effective way to save energy and reduce emissions, therefore, using recycled PET (R‐PET) to produce flame retardant PET could not only improved the recycling value of discarded PET, but also conducive to achieving carbon neutrality. The effects of melamine cyanurate (MCA), aluminum diethylphosphinate (ADP) and kaolin (Kaol) on flame retardant, combustion behavior, thermal degradation behaviors and mechanical properties of R‐PET composites were investigated by methods of limited oxygen index (LOI) measurement, vertical burning test, cone calorimeter test, thermogravimetry analysis (TG), SEM analysis and mechanical properties test. The results showed that MCA, ADP and Kaol could improve the flame retardant of R‐PET, and ADP had the best effect on improved the flame retardant of R‐PET. MCA and ADP had synergistic flame retardant in R‐PET, but MCA had a negative effect on the mechanical properties and thermal decomposition temperature of ADP/R‐PET composite. Kaol could not only improve the flame retardant and thermal decomposition temperature of MCA/ADP/R‐PET composites, but also improved their tensile and flexural strength. The flame retardant of 4‐Kaol/5‐MCA/15‐ADP/R‐PET composite reached UL94 1.0 mm V0 with LOI was 36.5%, and the tensile and flexural strength were increased by 26.1% and 16.7% compared with 5‐MCA/15‐ADP/R‐PET, respectively.

show abstract

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Preparation and property analysis of kaolin/melamine cyanurate/aluminum diethylphosphinate/recycled PET composites

Fang

2023

J of Applied Polymer Sci

View full text Add to dashboard Cite

show abstract

“…For this reason, such flame retardants cannot migrate and exude from the binder or a manufactured product. Oftentimes, reactive flame retardants not only increase the fire resistance properties and reduce the flammability of epoxy resins [34][35][36][37][38][39][40][41][42][43][44] but also improve the physical and mechanical properties of the final product [45][46][47].…”

Section: Introductionmentioning

confidence: 99%

Epoxy Compositions with Reduced Flammability Based on DER-354 Resin and a Curing Agent Containing Aminophosphazenes Synthesized in Bulk Isophoronediamine

et al. 2022

View full text Add to dashboard Cite

A method for the synthesis of an amine-containing epoxy resin curing agent by dissolving hexakis-[(4-formyl)phenoxy]cyclotriphosphazene in an excess of isophoronediamine was developed. The curing agent was characterized via NMR and IR spectroscopy and MALDI-TOF mass spectrometry, and its rheological characteristics were studied. Compositions based on DER-354 epoxy resin and the synthesized curing agent with different amounts of phosphazene content were obtained. The rheological characteristics of these compositions were studied, followed by their curing. An improvement in several thermal (DSC), mechanical (compression, tension, and adhesion), and physicochemical (water absorption and water solubility) characteristics, as well as the fire resistance of the obtained materials modified with phosphazene, was observed, compared with unmodified samples. In particular, there was an improvement in adhesive characteristics and fire resistance. Thus, compositions based on a curing agent containing a 30% modifier were shown to fulfill the V-1 fire resistance category. The developed compositions can be processed by contact molding, winding, and resin transfer molding (RTM), and the resulting material is suitable for use in aircraft, automotive products, design applications, and home repairs.

show abstract

Preparation of microencapsulated nitrogen‑phosphorus‑silicon flame retardant and its effect on high impact polystyrene flame retardancy

Sun,

Lu,

Liu

et al. 2023

Reactive and Functional Polymers

View full text Add to dashboard Cite

Flame retardancy effect of melamine cyanurate in combination with aluminum diethylphosphinate in a fully waterborne epoxy system

Cited by 3 publications

References 9 publications

Preparation and property analysis of kaolin/melamine cyanurate/aluminum diethylphosphinate/recycled PET composites

Preparation and property analysis of kaolin/melamine cyanurate/aluminum diethylphosphinate/recycled PET composites

Epoxy Compositions with Reduced Flammability Based on DER-354 Resin and a Curing Agent Containing Aminophosphazenes Synthesized in Bulk Isophoronediamine

Preparation of microencapsulated nitrogen‑phosphorus‑silicon flame retardant and its effect on high impact polystyrene flame retardancy

Contact Info

Product

Resources

About