In this study, we present the fabrication of a two-step
thermoresponsive
ultrafiltration (UF) membrane through polymerization of a lyotropic
liquid crystal (LLC). A mixture of commercially available Pluronic
F127 block copolymer, water (containing ammonium persulfate as the
initiator), and polymerizable oil (n-butyl acrylate/ethylene
glycol dimethacrylate) is used to create an LLC with a lamellar structure,
as characterized by cross-polarized light microscopy and atomic force
microscopy. Differential scanning calorimetry is employed to evaluate
the thermoresponsive behavior of the polymerized LLC (polyLLC). Two-step
thermoresponsiveness (∼35 and ∼50 °C) of the polyLLC
is observed due to the lower critical solution temperature (LCST)
of F127 and melting of the crystalline structure of the polyethylene
oxide (PEO) chains of the F127 surfactant. In the next step, the obtained
mesophase is cast on a nonwoven polyester support sheet followed by
thermal polymerization. The hydration capacity, water flux, water
flux recovery after fouling, and molecular weight cutoff (MWCO) of
the obtained membrane are evaluated at different temperatures to examine
its thermoresponsiveness. The experimental results reveal that the
UF membrane has a reversible thermoresponsive behavior at the LCST
and PEO melting of polyLLC. Additionally, the cleaning efficiency
of the fouled membrane can be enhanced by using its thermoresponsive
behavior, resulting in an extended lifetime of the product. Furthermore,
the MWCO of the membrane can be altered with temperature due to the
pore size change with temperature stimulus.