1984
DOI: 10.1063/1.446509
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Fluorescence of the Na*–N2 collision complex

Abstract: Articles you may be interested inThe study for the incipient solvation process of NaCl in water: The observation of the NaCl-(H2O) n (n = 1, 2, and 3) complexes using Fourier-transform microwave spectroscopy

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Cited by 19 publications
(23 citation statements)
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“…The concentration of carbon dioxide molecules N0 in flame was determined by the formula: At the processing of the experimental data the small contribution of water molecules in the broadening of Na-D lines was taken into account in the approximation ofbinary interactions between flame atoms and molecules5: K(Ac.r) = keff(LW)KHO(&T)NNaNHO (6) NNa N0 where kdic) is the measured effective absorption coefficient in the flame of the given molecular composition, KHO (Lo-) is the reduced absorption coefficient for Na-D lines broadened by iter molecules7 at Tfl=2125 K.…”
Section: Methodsmentioning
confidence: 99%
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“…The concentration of carbon dioxide molecules N0 in flame was determined by the formula: At the processing of the experimental data the small contribution of water molecules in the broadening of Na-D lines was taken into account in the approximation ofbinary interactions between flame atoms and molecules5: K(Ac.r) = keff(LW)KHO(&T)NNaNHO (6) NNa N0 where kdic) is the measured effective absorption coefficient in the flame of the given molecular composition, KHO (Lo-) is the reduced absorption coefficient for Na-D lines broadened by iter molecules7 at Tfl=2125 K.…”
Section: Methodsmentioning
confidence: 99%
“…More reliable data for potential parameters can be obtained taking into consideration independent experimental information to fix the ground state potential and additional experimental data on K(a) temperature dependency. 6. ACKNOWLEDGEMENTS This work was partially supported by a contract F-464 with Bulgarian Research Foundation.…”
Section: Check Of the Solutionmentioning
confidence: 97%
“…It is reasonable to assume, that the diabatic interaction does not inÑuence the quasi-static wing in emission and absorption, as the presence of the quenching channels of the exited states does not inÑuence the population of these states under conditions of thermodynamic equilibrium. However, the situation varies when the wing Ñuorescence proÐle [45] or excitation wing spectrum [46] are registered. In these cases the probability of quenching can depend on the distance between the Ñuorescence atom and the perturbing molecule and thereby inÑuence the registered proÐle of the quasi-static wing.…”
Section: T He Impact Approximationmentioning
confidence: 99%
“…If these potentials are known the normalized line shape can be unambiguously calculated [45]. But the inverse problem, namely, the restoration of interaction potentials on the base of the measured normalized SL proÐles, is incorrect in a general case, as it admits a multitude of decisions for and…”
Section: T He Problem Of Restoration Of Adiabatic Interaction Potentimentioning
confidence: 99%
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