The outcomes of the study of plant surfaces, such as rice leaves
or bamboo leaves, have led to extensive efforts being devoted to fabricating
anisotropic arrays of micro/nanoscale features for exploring anisotropic
droplet spreading. Nonetheless, precise engineering of the density
and continuity of three-phase contact lines for anisotropic wetting
remains a significant challenge without resorting to chemical modifications
and costly procedures. In this work, we investigated secondary electrohydrodynamic
instability in polymer films for producing secondary nanosized patterns
between the micrometer-sized grooves by controlling the timescale
parameter, 1/τm (>10–4 s–1). We experimentally demonstrated facile morphological control of
anisotropic wettability without the use of any chemical modifications.
Thus, anisotropic hydrophilic surfaces fabricated by the secondary
phase instability of polymer films are advantageous for both droplet
condensation and removal, thereby outperforming the water collection
efficiency of conventional (isotropic) hydrophilic surfaces in water
harvesting applications (∼200 mg·cm–2·h–1) with excellent durability.