2012
DOI: 10.1063/1.3684552
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Formation of silver nanoparticles inside a soda-lime glass matrix in the presence of a high intensity Ar+ laser beam

Abstract: Formation and motion of the silver nanoparticles inside an ion-exchanged soda-lime glass in the presence of a focused high intensity continuous wave Ar+ laser beam (intensity: 9.2 × 104 W/cm2) have been studied in here. One-dimensional diffusion equation has been used to model the diffusion of the silver ions into the glass matrix, and a two-dimensional reverse diffusion model has been introduced to explain the motion of the silver clusters and their migration toward the glass surface in the presence of the la… Show more

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Cited by 18 publications
(11 citation statements)
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“…In order to fit the experimental results obtained for the small nanoclusters, the permittivity of the PS-PAA polymer encapsulating the silver nanoclusters was modified to include a small imaginary part. Silver ions and impurities are known to diffuse into polymer, which in this case is enhanced by the higher temperatures during the encapsulation process, thus creating an effective absorbing medium 6 . Since the extinction coefficient κ depends on the ion and impurity concentration, it varies slightly from one sample to another.…”
mentioning
confidence: 99%
“…In order to fit the experimental results obtained for the small nanoclusters, the permittivity of the PS-PAA polymer encapsulating the silver nanoclusters was modified to include a small imaginary part. Silver ions and impurities are known to diffuse into polymer, which in this case is enhanced by the higher temperatures during the encapsulation process, thus creating an effective absorbing medium 6 . Since the extinction coefficient κ depends on the ion and impurity concentration, it varies slightly from one sample to another.…”
mentioning
confidence: 99%
“…We have previously demonstrated [14] that silver nanoparticles formed at the glass surface during the first few µs of the laser exposure, are embedded into a liquid glass phase and then pushed into the outer regions where the viscosity is lower than in the center of the spot. Previous reports have mentioned that the irradiated spots are free of silver nanoparticles in either Ag + -doped glasses or in composite glasses containing silver nanoparticles after intense cw laser exposure at 244 nm or in the visible range [14,24,25]. It is thus likely that the silver nanoparticles involved in the periodic arrangement come from the depth of the exchanged layer, where the initial silver ions concentration is much lower than at the glass surface.…”
Section: Discussionmentioning
confidence: 99%
“…For optimizing structural, optical and electrical properties of thin films, preparation techniques are usually combined by annealing process. [69][70][71][72][73][74][75][76][77] Annealing procedures can increase crystallinity and transmittance of thin films and reduce the defects of the crystalline structure. 65 78-80 In addition, studying of structural, morphological and optical properties of the prepared samples as a function of annealing temperature have been done and reported.…”
Section: Preparation Of Ag Thin Filmsmentioning
confidence: 99%