This work describes the seasonal and diurnal variations of downward longwave atmospheric irradiance (LW) at the surface in Sã o Paulo, Brazil, using 5-min-averaged values of LW, air temperature, relative humidity, and solar radiation observed continuously and simultaneously from 1997 to 2006 on a micrometeorological platform, located at the top of a 4-story building. An objective procedure, including 2-step filtering and dome emission effect correction, was used to evaluate the quality of the 9-yr-long LW dataset. The comparison between LW values observed and yielded by the Surface Radiation Budget project shows spatial and temporal agreement, indicating that monthly and annual average values of LW observed in one point of Sã o Paulo can be used as representative of the entire metropolitan region of Sã o Paulo. The maximum monthly averaged value of the LW is observed during summer (389 6 14 W m
22; January), and the minimum is observed during winter (332 6 12 W m 22 ; July). The effective emissivity follows the LW and shows a maximum in summer (0.907 6 0.032; January) and a minimum in winter (0.818 6 0.029; June). The mean cloud effect, identified objectively by comparing the monthly averaged values of the LW during clear-sky days and all-sky conditions, intensified the monthly average LW by about 32.0 6 3.5 W m 22 and the atmospheric effective emissivity by about 0.088 6 0.024. In August, the driest month of the year in Sã o Paulo, the diurnal evolution of the LW shows a minimum (325 6 11 W m 22 ) at 0900 LT and a maximum (345 6 12 W m 22 ) at 1800 LT, which lags behind (by 4 h) the maximum diurnal variation of the screen temperature. The diurnal evolution of effective emissivity shows a minimum (0.781 6 0.027) during daytime and a maximum (0.842 6 0.030) during nighttime. The diurnal evolution of all-sky condition and clear-sky day differences in the effective emissivity remain relatively constant (7% 6 1%), indicating that clouds do not change the emissivity diurnal pattern. The relationship between effective emissivity and screen air temperature and between effective emissivity and water vapor is complex. During the night, when the planetary boundary layer is shallower, the effective emissivity can be estimated by screen parameters. During the day, the relationship between effective emissivity and screen parameters varies from place to place and depends on the planetary boundary layer process. Because the empirical expressions do not contain enough information about the diurnal variation of the vertical stratification of air temperature and moisture in Sã o Paulo, they are likely to fail in reproducing the diurnal variation of the surface emissivity. The most accurate way to estimate the LW for clear-sky conditions in Sã o Paulo is to use an expression derived from a purely empirical approach.