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Impending health challenges in the formulations of particleboards from cellulosic-based waste particles such as wood chips, sawdust, and veneer boards are of great concern. These wastes are majorly bonded together with synthetic resin or binder in the presence of heat and pressure to produce particleboards of various specifications and sizes depending on the end-use. The qualities of the particleboards depend on the modification of the particle geometry, resin levels, board density, and manufacturing processes. The addition of special additives to enhance the qualitative performance of particleboards such as dimensional stability, fire retardancy enhancement, and moisture resistance is included in the manufacturing process. The milestone in the use of wood particles for particleboard manufacture is the large reduction in the environmental hazard that these abundant wastes cause. Furthermore, this review reports recent research efforts in the use of green adhesives to reduce the health threat related to utilizing formaldehyde-based particleboard. The use of adhesives produced from natural sources has contributed toward the reduction in the impending health challenges and the cost of building construction by using such a particleboard.
Impending health challenges in the formulations of particleboards from cellulosic-based waste particles such as wood chips, sawdust, and veneer boards are of great concern. These wastes are majorly bonded together with synthetic resin or binder in the presence of heat and pressure to produce particleboards of various specifications and sizes depending on the end-use. The qualities of the particleboards depend on the modification of the particle geometry, resin levels, board density, and manufacturing processes. The addition of special additives to enhance the qualitative performance of particleboards such as dimensional stability, fire retardancy enhancement, and moisture resistance is included in the manufacturing process. The milestone in the use of wood particles for particleboard manufacture is the large reduction in the environmental hazard that these abundant wastes cause. Furthermore, this review reports recent research efforts in the use of green adhesives to reduce the health threat related to utilizing formaldehyde-based particleboard. The use of adhesives produced from natural sources has contributed toward the reduction in the impending health challenges and the cost of building construction by using such a particleboard.
Conventional binders in the particleboards formulation involve use of formaldehyde resins. Epidemiologic studies show that formaldehyde is carcinogenic. Efforts to reduce formaldehyde emissions by use of scavengers has not been proven to reduce the emission. Molecular bonding of biobased adhesive molecules with lignocellulose materials provides an alternative way of producing composite material. In this study, maize stalk (MS), rice husks (RH) and sugarcane bagasse (SB) were used as sources of lignocellulose materials for particleboard formulation. SB, MS and RH were collected from their respective sites, sorted and dried. MS and RH were ground. Lignin content determination was done by drying lignocellulose material at 105 °C. Lignocellulose materials were prepared by hydrolysis of dried lignocellulose material with sodium hydroxide. Oxidized starch was prepared by oxidation of cassava peel starch using alkaline hydrogen peroxide. Particleboards were formulated through starch-lignocellulose polymerization at 60 °C compressed with 6.5 Nmm −2 pressure. Characterization of raw materials and formulated particleboards was done using XRD for mineralogical analysis, FTIR and NMR for elucidation of functional groups transformation. The results showed that esterification is the main process of chemical bonding in the particleboard formulation due to reaction between –COOH from starch and and OH- from lignocellulose. Etherification between hydroxyl groups from starch with hydroxyl groups from lignocellulose material. RH combined more through silication process with cassava peels starch than RH and SB showing materials containing high cellulose and hemicellulose content are more compatible. Composite materials formulated were used to produce medium density particleboards that can be used for making furniture and room partitioning.
The textile industry uses a lot of adhesives to join materials together, and many of these adhesives use petroleum-based ingredients that are harmful to the environment. To replace petroleum-based adhesives with a more environmentally friendly option for the textile industry, this study set out to create and evaluate a hot-melt adhesive derived from cassava starch. By adding kaolin clay as a filler and tannin as a tackifier in different ratios of starch, the created adhesive was enhanced. Tannic acid to starch ratios of 2:1, 6:1, and 10:1 w/w and kaolin to starch ratios of 3:1, 5:1, and 7:1 w/w were used to investigate the effects of clay and tackifier, respectively. The adhesives’s viscosity, moisture content, tensile strength, and shear strength were then measured. The presence of kaolin and tannic acid in starch-based adhesives favored a good interaction between the adhesive’s ingredients. The adhesive’s maximum shear strength was measured at 4.93 ± 0.11 Mpa when dry and 0.263 ± 0.21 Mpa when wet. The current data indicate that the optimal tensile strength was determined to be 3.45 ± 0.22 MPa. This result showed that hot melt adhesives based on cassava starch would be a good environmentally friendly substitute for petroleum-based adhesives, and more study in this field is necessary.
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