Fourier transform infrared spectroscopic study of the adsorption of multiple amino silane coupling agents on glass surfaces

Chiang, Chwan‐Hwa; Koenig, Jack L.

doi:10.1016/0021-9797(81)90331-3

Cited by 72 publications

(26 citation statements)

References 9 publications

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“…36 The FTIR studies of AEAPS films on high-specific-surface-area (fumed) silica were reported previously by Chiang and Koenig. 37 Based upon this work the assignments of the major observed bands are given in Table 2.…”

Section: Aminosilane Filmsmentioning

confidence: 99%

Spectroscopic quantification of covalently immobilized oligonucleotides

Saprigin

Thomas

Dulcey

et al. 2005

Surf. Interface Anal.

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Quantitative determination of surface coverage, film thickness and molecular orientation of DNA oligomers covalently attached to aminosilane self-assembled monolayers has been obtained using complementary infrared and photoelectron studies. Spectral variations between surface immobilized oligomers of the different nucleic acids are reported for the first time. Carbodiimide condensation was used for covalent attachment of phosphorylated oligonucleotides to silanized aluminum substrates. Fourier transform infrared (FTIR) spectroscopy and x-ray photoelectron spectroscopy (XPS) were used to characterize the surfaces after each modification step. Infrared reflection-absorption spectroscopy of covalently bound DNA provides orientational information. Surface density and layer thickness are extracted from XPS data. The surface density of immobilized DNA, 2-3 (×10 13 ) molecules cm −2 , was found to depend on base composition. Comparison of antisymmetric to symmetric phosphate stretching band intensities in reflection-absorption spectra of immobilized DNA and transmission FTIR spectra of DNA in KBr pellet indicates that the sugar-phosphate backbone is predominantly oriented with the sugar-phosphate backbone lying parallel to the surface, in agreement with the 10-20Å DNA film thickness derived from XPS intensities.

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Section: Aminosilane Filmsmentioning

confidence: 99%

Spectroscopic quantification of covalently immobilized oligonucleotides

Saprigin

Thomas

Dulcey

et al. 2005

Surf. Interface Anal.

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“…Fourier transform infrared spectroscopy (FTIR) has gained wide use in investigations into adsorption of silane molecules on silica surfaces (10,(15)(16)(17)(18)(19). 29 Si NMR has been used to study hydrolysis and condensation reactions of organosilanes (20,21), and magic angle spinning and cross-polarization 1 To whom correspondence should be addressed.…”

Section: Introductionmentioning

confidence: 99%

Silane Adsorption Behavior, Microstructure, and Properties of Glycidoxypropyltrimethoxysilane-Modified Colloidal Silica Coatings

Daniels

Francis

1998

Journal of Colloid and Interface Science

147

103

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“…The nature of absorbed coupling agent films deposited on glass, silica and other mineral surfaces has been studied extensively [5][6][7][8][9]. The reports show that multilayers are generally deposited onto mineral surfaces but a major portion of the deposited film is removed readily by water or organic solvents.…”

Section: Introductionmentioning

confidence: 99%

“…It is worth to add that Chiang and Koenig have found that coupling agents do not form a completely cured siloxane polymer on silica surface [9]. Their infra-red study of the adsorption of amine derivatives of silanes on fumed silica (Cab-O-Sil), performed after heat treatment to 130 ~ indicates an incomplete condensation of the silanol because a small shoulder at 940 cm -1 still remains in IR spectrum.…”

mentioning

confidence: 97%

Wettability of silane films on silica fillers

Marciniec

Krysztafkiewicz

Domka

1983

Colloid & Polymer Sci

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Heats of immersion in water/7,, vr and in benzene H, .~ (in joules per gramme) of four silica fillers, modified by some silane coupling agents capable of forming polisiloxane network, have been determined by using a calorimetric technique. The Hi w and Hp values as well as strength properties (tensile strength, 200% modulus) of the sulfur-cured SBR filled with the examined silicas are predominantly a function of specific surface of untreated filler and of content of a given silane deposited on the silica surface. A direct correlation between heats of immersion hi w and hp (in J/m 2) and silane surface coverage has been also found. Moreover the wettability parameters determined in water and benzene can be useful for evaluation of filler activity in elastomer reinforcement.

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Fourier transform infrared spectroscopic study of the adsorption of multiple amino silane coupling agents on glass surfaces

Cited by 72 publications

References 9 publications

Spectroscopic quantification of covalently immobilized oligonucleotides

Spectroscopic quantification of covalently immobilized oligonucleotides

Silane Adsorption Behavior, Microstructure, and Properties of Glycidoxypropyltrimethoxysilane-Modified Colloidal Silica Coatings

Wettability of silane films on silica fillers

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